Y-type zeolites for the catalytic oxidative degradation of organic azo dyes in wastewater


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Cobalt- and iron-containing catalysts active in the oxidation of organic dyes with hydrogen peroxide have been prepared from granular synthetic NaY and HY zeolites without a binder by ion exchange followed by heat treatment at 350–500°C. It has been demonstrated by X-ray photoelectron spectroscopy that cobalt and iron in these catalysts are in the form of Co2+ and Fe3+ ions on the support surface. The FeHY and CoNaY catalysts are most effective and stable in the oxidation of the anionic dye carmoisine in weakly acidic and alkaline media.

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M. Alekhina

Mendeleev University of Chemical Technology of Russia

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Email: mbalekhina@yandex.ru
俄罗斯联邦, Moscow, 125047

K. Khabirova

Mendeleev University of Chemical Technology of Russia

Email: mbalekhina@yandex.ru
俄罗斯联邦, Moscow, 125047

T. Kon’kova

Mendeleev University of Chemical Technology of Russia

Email: mbalekhina@yandex.ru
俄罗斯联邦, Moscow, 125047

I. Prosvirin

Boreskov Institute of Catalysis, Siberian Branch; Novosibirsk State University

Email: mbalekhina@yandex.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090

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