INTERACTION OF GOLD AND NICKEL NANOPARTICLES WITH MOLECULAR HYDROGEN AND CARBON MONOXIDE IN THE PRESENCE OF AN ELECTRIC FIELD

M V GRISHIN; Гришин М. В.; A K GATIN; Гатин А. К.; E K GOLUBEV; Голубев Е. К.; N. V.  DOKHLIKOVA; Дохликова Н. В.; S. A. OZERIN; Озерин С. А.; S. YU. SARVADI; Сарвадий С. Ю.; I. G. STEPANOV; Степанов И. Г.; V. G. SLUTSKII; Слуцкий В. Г.; V. A. KHARITONOV; Харитонов В. А.; B. R.  SHUB; Шуб Б. Р.

doi:10.31857/S0023291222600407

INTERACTION OF GOLD AND NICKEL NANOPARTICLES WITH MOLECULAR HYDROGEN AND CARBON MONOXIDE IN THE PRESENCE OF AN ELECTRIC FIELD

Authors: GRISHIN MV¹, GATIN AK¹, GOLUBEV EK², DOKHLIKOVA N.V.¹, OZERIN S.A.¹, SARVADI S.Y.¹, STEPANOV I.G.¹, SLUTSKII V.G.¹, KHARITONOV V.A.¹, SHUB B.R.¹
Affiliations:
1. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russia
2. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, Moscow, Russia
Issue: Vol 85, No 1 (2023)
Pages: 19-27
Section: Articles
Submitted: 16.10.2023
Published: 01.01.2023
URL: https://journal-vniispk.ru/0023-2912/article/view/137195
DOI: https://doi.org/10.31857/S0023291222600407
EDN: https://elibrary.ru/KEOADV
ID: 137195

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Abstract

A nanostructured gold–nickel coating has been synthesized on the surface of pyrolytic graphite. Its physicochemical properties have been studied by scanning tunneling microscopy and spectroscopy, Auger spectroscopy, mass spectrometry, and other methods. It has been found that the coating consists of clusters formed by gold and nickel nanoparticles. It has been shown that an electric field can inhibit or stimulate the adsorption of hydrogen on gold and the reduction of the oxidized surface of nickel nanoparticles with carbon monoxide. The mechanisms of the influence of the field on the chemical processes involving H2 and CO are different. Quantum-chemical simulation has made it possible to determine the values of the energy barriers for CO adsorption on nickel nanoparticles.

References

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