Synthesis and structural study of 3-phenyl-6,7,8,9-tetrahydrocyclopenta[ a ]naphthalene-containing  ansa -complexes of zirconium

V. V. Izmer; D. S. Kononovich; D. V. Uborsky; P. S. Kulyabin; N. E. Shevchenko; A. Z. Voskoboynikov

doi:10.3103/S002713141702002X

Synthesis and structural study of 3-phenyl-6,7,8,9-tetrahydrocyclopenta[a]naphthalene-containing ansa-complexes of zirconium

作者: Izmer V.V.¹, Kononovich D.S.¹, Uborsky D.V.¹, Kulyabin P.S.¹, Shevchenko N.E.¹, Voskoboynikov A.Z.¹
隶属关系:
1. Department of Chemistry
期: 卷 72, 编号 2 (2017)
页面: 97-103
栏目: Article
URL: https://journal-vniispk.ru/0027-1314/article/view/163422
DOI: https://doi.org/10.3103/S002713141702002X
ID: 163422

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The zirconium rac- and meso-complexes of the ansa-type that contain a 3-phenyl-6,7,8,9-tetrahydrocyclopenta[a]naphthalene fragment and a dimethylsilylene bridge are synthesized. The compounds obtained are characterized by NMR spectroscopy; the structure of rac-complex is studied by X-ray diffraction, which maked it possible to evaluate the steric availability of the zirconium center in the corresponding catalysts for the olefin polymerization.