Email this article Kinetic relationships of 90Sr sorption from aqueous solutions by carbonate-containing zirconium hydroxide Termoxid-3K
- Authors: Belokonova N.V.1, Voronina A.V.1
-
Affiliations:
- Yeltsin Ural Federal University
- Issue: Vol 67, No 2 (2025)
- Pages: 135-142
- Section: Articles
- URL: https://journal-vniispk.ru/0033-8311/article/view/308137
- DOI: https://doi.org/10.31857/S0033831125020048
- ID: 308137
Cite item
Open Access
Access granted
Subscription Access
Abstract
The kinetic relationships of the 90Sr sorption from fresh water by Termoxid-3K inorganic sorbent were studied. The influence of the solution stirring rate, strontium concentration, and temperature on the sorption rate constant, diffusion coefficients, and kinetic regime was investigated, and the experimental results obtained were modeled using models of diffusion and chemical kinetics. The strontium sorption onto T-3K sorbent has a two-stage character and proceeds in the internal diffusion mode with a limiting contribution of the chemisorption process in the first stage. The diffusion coefficients of strontium were 10–12–10–13 m2/s, and the activation energy in the first stage of sorption was 93.3 and at the second stage, 23.8 kJ/mol.
About the authors
N. V. Belokonova
Yeltsin Ural Federal University
Author for correspondence.
Email: av.voronina@mail.ru
620002, Yekaterinburg, ul. Mira 19
A. V. Voronina
Yeltsin Ural Federal University
Email: av.voronina@mail.ru
620002, Yekaterinburg, ul. Mira 19
References
- Yi I.-G., Kang J.-K., Lee S.-C., Lee C.-G., Kim S.-B. // Micropor. Mesopor. Mater. 2019. Vol. 279. P. 45–52.
- Bochkarev G.R., Pushkareva G.I. // J. Min. Sci. 2009. Vol. 45. P. 290–294.
- Başçetin E., Atun G. // J. Chem. Eng. Data. 2010. Vol. 55. N 2. P. 783–788.
- Boyd G.E., Adamson A.W., Myers L.S., Jr. // J. Am. Chem. Soc. 1947. Vol. 69. N 11. P. 2836–2848.
- Merceille A., Weinzaepfel E., Barré Y., Grandjean A. // Sep. Purif. Technol. 2012. Vol. 96. P. 81–88.
- Missana T., Garcia-Gutierrez M., Alonso U. // Phys. Chem. Earth. Parts A/B/C. 2008. Vol. 33. Suppl. 1. P. S156–S162.
- Abdel-Karim A.M., Zaki A.A., Elwan W., El-Naggar M.R., Gouda M.M. // Appl. Clay Sci. 2016. Vol. 132–133. P. 391–401.
- Kamel N.H.M. // J. Environ. Radioact. 2010. Vol. 101. N 4. P. 297–303.
- Ma B., Oh S., Shin W.S., Choi S.-J. // Desalination. 2011. Vol. 276. P. 336–346.
- Chen Y., Wang J. // Nucl. Eng. Des. 2012. Vol. 242. P. 445–451.
- Недобух Т.А., Захарова Т.С., Воронина А.В., Кутергин А.С., Семенищев В.С. // Сорбционные и хроматографические процессы. 2022. Т. 22. № 4. С. 473–484.
- Voronina A.V., Bajtimirova M.O., Semenishchev V.S. // J. Radioanal. Nucl. Chem. 2022. Vol. 331. N 2. P. 913–920.
- Fei C., Linlin Y., Fei G., Xiao G., Qiang X., Zhen Z., Feng Z., Jingguang F. // Radiat. Med. Prot. 2022. Vol. 3. N 2. P. 96–100.
- Bezhin N.A., Dovhyi I.I., Milyutin V.V., Nekrasova N.A., Tokar’ E.A., Tananaev I.G. // Radiochemistry. 2019. Vol. 61. P. 700–706.
- Mironyuk I., Mykytyn I., Vasylyeva H., Savka K. // J. Mol. Liq. 2020. Vol. 316. ID 113840.
- Kononenko O.A., Milyutin V.V., Kaptakov V.O., Makarenkov V.I., Kozlitin E.A. // J. Radioanal. Nucl. Chem. 2024. Vol. 333. P. 4889–4897.
- Singh O.V., Tandon S.N. // Int. J. Appl. Radiat. Isot. 1977. Vol. 28. N 8. P. 701–704.
- Matskevich A.I., Tokar E.A., Sokolnitskaya T.A., Markin N.S., Priimak I.D., Egorin A.M. // J. Radioanal. Nucl. Chem. 2022. Vol. 331. P. 5691–5699.
- Shashkova I., Kitikova N., Sycheva O., Dzikaya A., Nurbekova M., Hosseini-Bandegharaei A., Ivanets A. // Ceram. Int. 2024. Vol. 50. N 13. Part A. P. 22836–22847.
- Mudruk N., Maslova M. // Int. J. Mol. Sci. 2023. Vol. 24. N 9. ID 7903.
- Matel L., Dulanska S., Silikova V. // XXXIX Days of Radiation Protection. Proc. Presentations and Posters. Bratislava, Nov. 6–10, 2017. P. 578.
- Tel H., Altaş, Y., Eral M., Sert, Ş., Çetinkaya B., İnan S. // Chem. Eng. J. 2010. Vol. 161. P. 151–160.
- Belokonova N.V., Tarasovskikh T.V., Voronina A.V. // AIP Conf. Proc. 2022. Vol. 2466. ID 050043. https://doi.org/10.1063/5.0088731
- Voronina A.V., Noskova A.Yu., Semenishchev V.S., Gupta D.K. // J. Environ. Radioact. 2020. Vol. 217. ID 106210.
- Никифоров А.Ф., Юрченко В.В. // Сорбционные и хроматографические процессы. 2010. Т. 10. № 5. С. 676–684.
- Mironyuk I., Tatarchuk T., Vasylyeva H., Naushad Mu., Mykytyn I. // J. Environ. Chem. Eng. 2019. Vol. 7. N 6. ID 103430.
- Li D., Zhang B., Xuan F. // J. Mol. Liq. 2015. Vol. 209. P. 508–514.
- Ripon R.I., Begum Z.A., Ahmmad B., Hirose F., Takagai Y., Rahman I.M.M. // J. Environ. Chem. Eng. 2024. Vol. 12. N 5. ID 113984.
- Shashkova I.L., Ivanets A.I., Kitikova N.V., Sillanpää M. // J. Taiwan Inst. Chem. Eng. 2017. Vol. 80. P. 787–796.
- Maslova M.V., Ivanenko V.I., Gerasimova L.G. // Russ. J. Phys. Chem. A. 2019. Vol. 93. N 7. P. 1245–1251.
- Voronina A.V., Belokonova N.V. // Radiochemistry. 2023. Vol. 65. N 4. P. 473–484.
- Voronina A.V., Belokonova N.V., Suetina A.K., Semenishchev V.S. // J. Radioanal. Nucl. Chem. 2022. Vol. 331. P. 4021–4030.
- Воронина А.В., Белоконова Н.В., Суетина А.К. Патент RU 2796325 C1. Опубл. 22.05.2023.
- Кокотов Ю.А., Пасечник В.А. Равновесие и кинетика ионного обмена. Л.: Химия, 1970. 336 с.
- Гельферих Ф. Иониты. М.: Изд-во иностр. лит., 1962. 490 с.
- Киекпаев М.А., Строева Э.В. // Вестн. ОГУ. 2006. № 5. С. 35–39.
- Эмануэль Н.М., Кнорре Д.Г. Курс химической кинетики: учебник для химических факультетов. М.: ВШ, 1974. 3-е изд. 400 с.
Supplementary files
