Phase equilibria in the PbBi2S4–PbSnS2 system


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Abstract

The PbBi2S4–PbSnS2 system was studied by physicochemical analysis methods, and its state diagram was constructed. The system is partially quasi-binary; regions of solid solutions based on PbSnS2 are determined. At a ratio between the initial components of 1: 1, congruently melting compound Pb2SnBi2S6 forms. The unit cells parameters of Pb2SnBi2S6 crystallizing in the orthorhombic system are: a = 15.60 Å, b = 7.80 Å, c = 4.26 Å; space group Pbmm.

About the authors

G. R. Gurbanov

Azerbaijan State Oil Academy

Author for correspondence.
Email: ebikib@mail.ru
Azerbaijan, Baku

Sh. G. Mamedov

Nagiev Institute of Catalysis and Inorganic Chemistry

Email: ebikib@mail.ru
Azerbaijan, Baku

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