Email this article Physicochemical Analysis of the System Zr(SO4)2–Na2SO4–H2SO4–H2O at 25°С
- Authors: Shulyak D.V.1, Skiba G.S.1, Kuznetsov V.Y.1
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Affiliations:
- Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Research Center
- Issue: Vol 61, No 6 (2016)
- Pages: 776-780
- Section: Physicochemical Analysis of Inorganic Systems
- URL: https://journal-vniispk.ru/0036-0236/article/view/166554
- DOI: https://doi.org/10.1134/S0036023616060188
- ID: 166554
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Abstract
The solubility in the quaternary water–salt system Zr(SO4)2 · 4Н2О–Na2SO4–H2SO4–H2O at 25°C was studied. It was found that, in the system, there is crystallization of not only Na2SO4 and Zr(SO4)4 · 4H2O, but also sodium sulfate zirconates Na2Zr(SO4)2(OH)2 · 0.3H2O, Na4Zr(SO4)4 · 3H2O, and Na2Zr(SO4)2 · 3H2O and two new compounds, S1 and S2, which are presumably Na2ZrO(SO4)2 · 2H2O and Na2Zr2O2(SO4)3 · 6H2O.
About the authors
D. V. Shulyak
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Research Center
Author for correspondence.
Email: shulyak@chemy.kolasc.net.ru
Russian Federation, ul. Fersmana 26A, Apatity, Murmansk oblast, 184200
G. S. Skiba
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Research Center
Email: shulyak@chemy.kolasc.net.ru
Russian Federation, ul. Fersmana 26A, Apatity, Murmansk oblast, 184200
V. Ya. Kuznetsov
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Research Center
Email: shulyak@chemy.kolasc.net.ru
Russian Federation, ul. Fersmana 26A, Apatity, Murmansk oblast, 184200
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