Conformation of diethylglyoxime in uranyl complexes

A. G. Beirakhov; I. M. Orlova; A. V. Rotov; E. G. Il’in; L. V. Goeva; M. D. Surazhskaya; A. V. Churakov; Yu. N. Mikhailov

doi:10.1134/S0036023616120032

Conformation of diethylglyoxime in uranyl complexes

Authors: Beirakhov A.G.¹, Orlova I.M.¹, Rotov A.V.¹, Il’in E.G.¹, Goeva L.V.¹, Surazhskaya M.D.¹, Churakov A.V.¹, Mikhailov Y.N.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry
Issue: Vol 61, No 12 (2016)
Pages: 1522-1529
Section: Coordination Compounds
URL: https://journal-vniispk.ru/0036-0236/article/view/166951
DOI: https://doi.org/10.1134/S0036023616120032
ID: 166951

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Abstract

New complexes of uranyl with diethylglyoxime have been synthesized and studied. A feature of these complexes is the tetradentate bridging coordination of the ligand in both cis- and trans-conformations. The structure of organic ligand C₆H₁₂N₂O₂ and binuclear complex (CN₃H₆)₄[(UO₂)₂(C₆H₁₀N₂O₂)(CO₃)(C₂O₄)₂] ∙ H₂O have been determined by X-ray diffraction.