Copper(II) complexation with 1-methyl-2-mercaptoimidazole in 7 M HCl
- Authors: Amindzhanov A.A.1, Manonov K.A.2, Kabirov N.G.2, Abdelrahman G.A.2
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Affiliations:
- Faculty of Chemistry
- Research Institute
- Issue: Vol 61, No 1 (2016)
- Pages: 81-85
- Section: Physical Methods of Investigation
- URL: https://journal-vniispk.ru/0036-0236/article/view/167065
- DOI: https://doi.org/10.1134/S0036023616010034
- ID: 167065
Cite item
Abstract
The complexation of copper(II) with 1-methyl-2-mercaptoimidazole in 7 M HCl was potentiometrically studied. The compositions of complexes were determined, and their stepwise formation constants were calculated. The complexes were shown to become less stable with increasing temperature. The thermodynamic functions of complexation were estimated. The copper complexes were shown to surpass the rhenium complexes in stability.
Keywords
About the authors
A. A. Amindzhanov
Faculty of Chemistry
Author for correspondence.
Email: azimjon51@mail.ru
Tajikistan, ul. Rudaki 17, Dushanbe, 734025
K. A. Manonov
Research Institute
Email: azimjon51@mail.ru
Tajikistan, ul. Rudaki 17, Dushanbe, 734025
N. G. Kabirov
Research Institute
Email: azimjon51@mail.ru
Tajikistan, ul. Rudaki 17, Dushanbe, 734025
Gamal Abdelaziz Hussein Abdelrahman
Research Institute
Email: azimjon51@mail.ru
Tajikistan, ul. Rudaki 17, Dushanbe, 734025
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