Email this article Synthesis and crystal structure of hexakis(ε-caprolactam)lutetium(III) hexa(isothiocyanato)chromate(III) bis(ε-caprolactam) solvate
- Authors: Cherkasova E.V.1, Peresypkina E.V.2,3, Virovets A.V.2,3, Cherkasova T.G.1
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Affiliations:
- Gorbachev Kuzbass State Technical University
- Nikolaev Institute of Inorganic Chemistry
- Novosibirsk State University
- Issue: Vol 61, No 4 (2016)
- Pages: 447-450
- Section: Coordination Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/167270
- DOI: https://doi.org/10.1134/S0036023616040070
- ID: 167270
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Abstract
The reaction between Lu(NO3)3, K3[Cr(NCS)6], and ε-caprolactam (ε-C6H11NO) in an aqueous solution afforded complex [Lu(ε-C6H11NO)6][Cr(NCS)6] · 2(ε-C6H11NO) (I), the structure of which was determined by IR spectroscopy and X-ray diffraction. Crystals of I are triclinic, space group \(P\bar 1\), Z = 1, a = 12.1371(7) Å, b = 12.2082(7) Å, c = 12.7090(7) Å, α = 67.2920(10)°, β = 87.9130(10)°, γ = 82.9410(10)°, V = 1723.86(17) Å3, ρcalc = 1.426 g/cm3.
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About the authors
E. V. Cherkasova
Gorbachev Kuzbass State Technical University
Author for correspondence.
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
E. V. Peresypkina
Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
A. V. Virovets
Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
T. G. Cherkasova
Gorbachev Kuzbass State Technical University
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
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