Study of the factors affecting the formation of copper–chromium/aluminum oxide compounds with a spinel structure

Abstract

The effect of the Cr³⁺/Al³⁺ ratio on the crystallization temperature of mixed oxide compounds with a spinel structure and their structural features and morphological characteristics have been studied using a combination of physicochemical methods: thermal analysis, IR spectroscopy, X-ray powder diffraction, and electron microscopy. The role of temperature of synthesis and drying of Cu–Cr/Al hydroxy precursors in the formation of copper-containing spinels CuCr_xAl_2–xO₄, where x = 0–2, has been elucidated. The results are of interest for selection of the optimal composition and conditions of synthesis and formation of copper-containing spinels for their practical use.