Study of the factors affecting the formation of copper–chromium/aluminum oxide compounds with a spinel structure


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The effect of the Cr3+/Al3+ ratio on the crystallization temperature of mixed oxide compounds with a spinel structure and their structural features and morphological characteristics have been studied using a combination of physicochemical methods: thermal analysis, IR spectroscopy, X-ray powder diffraction, and electron microscopy. The role of temperature of synthesis and drying of Cu–Cr/Al hydroxy precursors in the formation of copper-containing spinels CuCrxAl2–xO4, where x = 0–2, has been elucidated. The results are of interest for selection of the optimal composition and conditions of synthesis and formation of copper-containing spinels for their practical use.

作者简介

I. Simentsova

Boreskov Institute of Catalysis, Siberian Branch

编辑信件的主要联系方式.
Email: sii@catalysis.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090

L. Plyasova

Boreskov Institute of Catalysis, Siberian Branch

Email: sii@catalysis.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090

N. Shtertser

Boreskov Institute of Catalysis, Siberian Branch; Novosibirsk State University

Email: sii@catalysis.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090

T. Minyukova

Boreskov Institute of Catalysis, Siberian Branch

Email: sii@catalysis.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090

V. Zaikovskii

Boreskov Institute of Catalysis, Siberian Branch; Novosibirsk State University

Email: sii@catalysis.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090

E. Paukshtis

Boreskov Institute of Catalysis, Siberian Branch

Email: sii@catalysis.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090

T. Yurieva

Boreskov Institute of Catalysis, Siberian Branch

Email: sii@catalysis.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090

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