Synthesis and magnetic properties of solid solutions In1–xGaxSb〈Mn〉


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Abstract

Manganese-doped solid solutions In1–xGaxSb (x = 0.05, 0.1, 0.5, 0.9, 0.95) were synthesized. It was found that, in samples of the compositions In0.95Ga0.05Sb〈Mn〉 and In0.05Ga0.95Sb〈Mn〉, a homogeneous substitutional solid solution forms, into which manganese-containing clusters are incorporated. The clusters are mainly located at crystal lattice defects—grain boundaries and dislocations. The ferromagnetic properties of the obtained samples at room temperature and higher are caused by clusters Mn1+xSb, the effective size of which is about 180–300 nm.

About the authors

O. N. Pashkova

Kurnakov Institute of General and Inorganic Chemistry

Author for correspondence.
Email: olg-pashkova@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

A. D. Izotov

Kurnakov Institute of General and Inorganic Chemistry

Email: olg-pashkova@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

N. N. Lobanov

Peoples’ Friendship University of Russia

Email: olg-pashkova@yandex.ru
Russian Federation, ul. Miklukho-Maklaya 6, Moscow, 117198

V. P. Sanygin

Kurnakov Institute of General and Inorganic Chemistry

Email: olg-pashkova@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

A. V. Filatov

Kurnakov Institute of General and Inorganic Chemistry

Email: olg-pashkova@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

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