Association of bromate ion in nonaqueous solutions of alkali metal salts


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Abstract

Manifestations of ion association of lithium cation with BrO3- ion in the vibrational spectrum have been studied by IR spectroscopy. The microstructure of the bromate ion with lithium cation in a contact ion pair in an aprotic solvent has been determined by the density functional theory method in the B3LYP/cc-pVTZ approximation, and the vibrational spectrum of coordinated bromate ion has been calculated.

About the authors

G. P. Mikhailov

Ufa State Aviation Technical University

Author for correspondence.
Email: gpmihailov@mail.ru
Russian Federation, Ufa, Bashkortostan, 450000

L. V. Rabchuk

Ufa State Aviation Technical University

Email: gpmihailov@mail.ru
Russian Federation, Ufa, Bashkortostan, 450000

V. V. Lazarev

Ufa State Aviation Technical University

Email: gpmihailov@mail.ru
Russian Federation, Ufa, Bashkortostan, 450000

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