Onium salts of sulfur-containing oxyanions resulting from reaction of sulfur(IV) oxide with aqueous solutions of 1,2-diamines and morpholine


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

Reaction products have been isolated from SO2–L–H2O–О2 systems (L = ethylenediamine, N,N,N′,N′-tetramethylethylenediamine, piperazine, and morpholine) as onium salts [H3NCH2CH2NH3]SO4, [(CH3)2NHCH2CH2NH(CH3)2]SO4, [(CH3)2NHCH2CH2NH(CH3)2]S2O6 ⋅ H2O, [C4H8N2H4]SO3 ⋅ H2O, [C4H8N2H4]S2O6, [C4H8N2H4]SO4 ⋅ H2O, [O(C2H4)2NH2]2SO4 ⋅ H2O. The prepared compounds have been characterized by X-ray diffraction analysis, X-ray powder diffraction, IR and mass spectroscopy.

About the authors

R. E. Khoma

Physicochemical Institute for Environment and Human Protection; Odessa National University

Author for correspondence.
Email: rek@onu.edu.ua
Ukraine, Odessa, 65082; Odessa, 65082

V. O. Gel’mbol’dt

Odessa National Medical University

Email: rek@onu.edu.ua
Ukraine, Odessa, 65082

A. A. Ennan

Physicochemical Institute for Environment and Human Protection

Email: rek@onu.edu.ua
Ukraine, Odessa, 65082

V. N. Baumer

Institute of Single Crystals

Email: rek@onu.edu.ua
Ukraine, Kharkov, 61001

A. N. Puzan

Institute of Single Crystals

Email: rek@onu.edu.ua
Ukraine, Kharkov, 61001

T. V. Koksharova

Odessa National University

Email: rek@onu.edu.ua
Ukraine, Odessa, 65082

A. V. Mazepa

Bogatskii Physicochemical Institute

Email: rek@onu.edu.ua
Ukraine, Odessa, 65080

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2017 Pleiades Publishing, Ltd.