Onium salts of sulfur-containing oxyanions resulting from reaction of sulfur(IV) oxide with aqueous solutions of 1,2-diamines and morpholine
- Authors: Khoma R.E.1,2, Gel’mbol’dt V.O.3, Ennan A.A.1, Baumer V.N.4, Puzan A.N.4, Koksharova T.V.2, Mazepa A.V.5
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Affiliations:
- Physicochemical Institute for Environment and Human Protection
- Odessa National University
- Odessa National Medical University
- Institute of Single Crystals
- Bogatskii Physicochemical Institute
- Issue: Vol 62, No 6 (2017)
- Pages: 736-745
- Section: Coordination Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/167727
- DOI: https://doi.org/10.1134/S0036023617060109
- ID: 167727
Cite item
Abstract
Reaction products have been isolated from SO2–L–H2O–О2 systems (L = ethylenediamine, N,N,N′,N′-tetramethylethylenediamine, piperazine, and morpholine) as onium salts [H3NCH2CH2NH3]SO4, [(CH3)2NHCH2CH2NH(CH3)2]SO4, [(CH3)2NHCH2CH2NH(CH3)2]S2O6 ⋅ H2O, [C4H8N2H4]SO3 ⋅ H2O, [C4H8N2H4]S2O6, [C4H8N2H4]SO4 ⋅ H2O, [O(C2H4)2NH2]2SO4 ⋅ H2O. The prepared compounds have been characterized by X-ray diffraction analysis, X-ray powder diffraction, IR and mass spectroscopy.
About the authors
R. E. Khoma
Physicochemical Institute for Environment and Human Protection; Odessa National University
Author for correspondence.
Email: rek@onu.edu.ua
Ukraine, Odessa, 65082; Odessa, 65082
V. O. Gel’mbol’dt
Odessa National Medical University
Email: rek@onu.edu.ua
Ukraine, Odessa, 65082
A. A. Ennan
Physicochemical Institute for Environment and Human Protection
Email: rek@onu.edu.ua
Ukraine, Odessa, 65082
V. N. Baumer
Institute of Single Crystals
Email: rek@onu.edu.ua
Ukraine, Kharkov, 61001
A. N. Puzan
Institute of Single Crystals
Email: rek@onu.edu.ua
Ukraine, Kharkov, 61001
T. V. Koksharova
Odessa National University
Email: rek@onu.edu.ua
Ukraine, Odessa, 65082
A. V. Mazepa
Bogatskii Physicochemical Institute
Email: rek@onu.edu.ua
Ukraine, Odessa, 65080
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