Email this article Reaction of the [B10H9O2C4H8]– anion with C-nucleophiles
- Authors: Matveev E.Y.1,2, Akimov S.S.3, Kubasov A.S.1, Nichugovskii A.I.2, Nartov A.S.4, Retivov V.M.4, Zhizhin K.Y.1,2, Kuznetsov N.T.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Moscow Technological University (MITHT)
- Chimmed Ltd.
- Federal State Unitary Enterprise “Research Institute of Chemical Reagents and High-Purity Chemical Substances”
- Issue: Vol 62, No 6 (2017)
- Pages: 808-813
- Section: Physical Methods of Investigation
- URL: https://journal-vniispk.ru/0036-0236/article/view/167769
- DOI: https://doi.org/10.1134/S0036023617060146
- ID: 167769
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Abstract
The reactions of 1,4-dioxane-substituted closo-decaborate anion ([B10H9O2C4H8]–) with metal acetylenides, diethyl malonate, ethyl acetoacetate, triethyl orthoformate, acetylacetone, and malonodinitrile were studied. The reactions were shown to be accompanied with substituent ring opening and attachment of the corresponding pendant functional group. The obtained compounds were characterized by various physicochemical methods (IR and polynuclear NMR spectroscopy, ESI mass spectrometry).
About the authors
E. Yu. Matveev
Kurnakov Institute of General and Inorganic Chemistry; Moscow Technological University (MITHT)
Email: zhizhin@igic.ras.ru
Russian Federation, Moscow, 117907; Moscow, 119571
S. S. Akimov
Chimmed Ltd.
Email: zhizhin@igic.ras.ru
Russian Federation, Moscow, 115230
A. S. Kubasov
Kurnakov Institute of General and Inorganic Chemistry
Email: zhizhin@igic.ras.ru
Russian Federation, Moscow, 117907
A. I. Nichugovskii
Moscow Technological University (MITHT)
Email: zhizhin@igic.ras.ru
Russian Federation, Moscow, 119571
A. S. Nartov
Federal State Unitary Enterprise “Research Institute of Chemical Reagents and High-Purity Chemical Substances”
Email: zhizhin@igic.ras.ru
Russian Federation, Moscow, 107076
V. M. Retivov
Federal State Unitary Enterprise “Research Institute of Chemical Reagents and High-Purity Chemical Substances”
Email: zhizhin@igic.ras.ru
Russian Federation, Moscow, 107076
K. Yu. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry; Moscow Technological University (MITHT)
Author for correspondence.
Email: zhizhin@igic.ras.ru
Russian Federation, Moscow, 117907; Moscow, 119571
N. T. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry
Email: zhizhin@igic.ras.ru
Russian Federation, Moscow, 117907
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