New double complex salt [PdEn2]3[Rh(NO2)6]2 · 2.67H2O: Synthesis, crystal structure, and thermal properties


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The crystal structure of the double complex salt (DCS) [PdEn2]3[Rh(NO2)6]2 • 2.67H2O (I) has been determined by X-ray diffraction. Crystals are triclinic, space group \(P\bar 1\), Z = 4, a = 9.2331(3) Å, b = 9.9136(4) Å, c = 13.7824(5) Å, α = 84.3230(14)°, β = 89.9655(14)°, γ = 66.7272(13)°, V = 1152.19(7) Å3, ρcalcd = 2.141 g/cm3, R = 0.0279. The thermal behavior of complex salt I has been studied in various gas atmospheres. The end product of thermolysis in reductive atmosphere is a mixture of Pd0.45Rh0.55 and Pd0.95Rh0.05 solid solutions. The end product of thermolysis in an inert atmosphere is a homogeneous Pd0.6Rh0.4 solid solution.

作者简介

A. Kirilovich

Novosibirsk State University

Email: plus@niic.nsc.ru
俄罗斯联邦, ul. Pirogova 2, Novosibirsk, 630090

P. Plyusnin

Novosibirsk State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch

编辑信件的主要联系方式.
Email: plus@niic.nsc.ru
俄罗斯联邦, ul. Pirogova 2, Novosibirsk, 630090; pr. Akademika Lavrent’eva 3, Novosibirsk, 630090

D. Piryazev

Novosibirsk State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch

Email: plus@niic.nsc.ru
俄罗斯联邦, ul. Pirogova 2, Novosibirsk, 630090; pr. Akademika Lavrent’eva 3, Novosibirsk, 630090

S. Gromilov

Novosibirsk State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch

Email: plus@niic.nsc.ru
俄罗斯联邦, ul. Pirogova 2, Novosibirsk, 630090; pr. Akademika Lavrent’eva 3, Novosibirsk, 630090

S. Korenev

Novosibirsk State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch

Email: plus@niic.nsc.ru
俄罗斯联邦, ul. Pirogova 2, Novosibirsk, 630090; pr. Akademika Lavrent’eva 3, Novosibirsk, 630090

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