Copper(II), nickel(II), and zinc(II) complexes with  o -tozylaminobenzaldehyde 4,6-dimethylpyrimidyl hydrazone

L. D. Popov; V. V. Tkachev; Yu. P. Tupolova; S. A. Borodkin; G. V. Shilov; E. A. Ugolkova; O. I. Askalepova; A. S. Burlov; V. V. Lukov; I. N. Shcherbakov; S. I. Levchenkov; V. V. Minin

doi:10.1134/S003602361707018X

Copper(II), nickel(II), and zinc(II) complexes with o-tozylaminobenzaldehyde 4,6-dimethylpyrimidyl hydrazone

Authors: Popov L.D.¹, Tkachev V.V.², Tupolova Y.P.¹, Borodkin S.A.¹, Shilov G.V.², Ugolkova E.A.³, Askalepova O.I.¹, Burlov A.S.⁴, Lukov V.V.¹, Shcherbakov I.N.¹, Levchenkov S.I.⁵, Minin V.V.³
Affiliations:
1. Southern Federal University
2. Institute of Problems of Chemical Physics
3. Kurnakov Institute of General and Inorganic Chemistry
4. Institute of Physical and Organic Chemistry
5. Southern Scientific Center
Issue: Vol 62, No 7 (2017)
Pages: 893-899
Section: Coordination Compounds
URL: https://journal-vniispk.ru/0036-0236/article/view/167816
DOI: https://doi.org/10.1134/S003602361707018X
ID: 167816

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Abstract

o-Tosylaminobenzaldehyde dimethylpyrimidyl hydrazone and its copper(II), nickel(II), and zinc(II) complexesare synthesized and studied. According to the X-ray diffraction data, the zinc(II) complex has the structure of a tetragonal pyramid with the N₃O donor ligand environment. According to EPR and magnetochemistry data, the copper(II) complex has a similar structure of the chelate core. In the nickel(II) complex, the solvent molecule completes the coordination core to an octahedron.