Email this article Structural features of monomeric octahedral d2-rhenium(V) monooxo complexes with oxygen atoms of bidentate-chelating neutral and acidic ligands (O,P)
- Authors: Sergienko V.S.1,2, Churakov A.V.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- All-Russia Institute for Scientific and Technical Information
- Issue: Vol 62, No 10 (2017)
- Pages: 1327-1342
- Section: Coordination Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/168079
- DOI: https://doi.org/10.1134/S0036023617100151
- ID: 168079
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Abstract
The structural features of 38 mononuclear d2-Re(V) octahedral monooxo complexes (I–XXXVIII) with oxygen atoms of bidentate-chelating (O, P) ligands (Ln) are considered. The atoms O(Ln) are mostly in trans positions to O(oxo) ligands. In three compounds of general formula [ReO(Lmono)(Ln)2] (XXXVI–XXXVIII), the O atoms of two Ln ligands occupy both trans and cis positions to oxo ligands. In one complex, namely, in [ReO(Ln)(Ltri11)], n = 3 (XXXV), the atom O(L3) is in the cis position to the oxo ligand; the trans position to O(oxo) is occupied by the atom O(Ltri11).
About the authors
V. S. Sergienko
Kurnakov Institute of General and Inorganic Chemistry; All-Russia Institute for Scientific and Technical Information
Email: churakov@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 125190
A. V. Churakov
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: churakov@igic.ras.ru
Russian Federation, Moscow, 119991
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