Email this article Scheelite-Related Triple Molybdates KCaLn(MoO4)3 in K2MoO4–CaMoO4–Ln2(MoO4)3 (Ln = Nd, Sm, Eu, Gd) Systems: Synthesis and Characterization
- Authors: Kozhevnikova N.M.1
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Affiliations:
- Baikal Institute for Nature Management, Siberian Branch
- Issue: Vol 63, No 2 (2018)
- Pages: 157-161
- Section: Synthesis and Properties of Inorganic Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/168386
- DOI: https://doi.org/10.1134/S0036023618020146
- ID: 168386
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Abstract
Subsolidus phase ratios in K2MoO4–CaMoO4–Ln2(MoO4)3 systems where Ln = Nd, Sm, Eu, and Gd, have been studied by vibrational spectroscopy, X-ray powder diffraction, and differential thermal analysis. Triple molybdates KCaLn(MoO4)3 (Ln = Nd, Sm, Eu, and Gd) have been synthesized; they have a scheelite-derivative structure, monoclinic crystal system (space group P21/n). Their unit cell parameters have been determined, and IR and Raman spectra characterized.
About the authors
N. M. Kozhevnikova
Baikal Institute for Nature Management, Siberian Branch
Author for correspondence.
Email: nicas@binm.ru
Russian Federation, Ulan-Ude, 670047
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