Synthesis and Crystal Structure of Tetrakis(dimethyl sulfoxide)copper(II) Hexafluorosilicate

T. G. Cherkasova; N. V. Pervukhina; N. V. Kuratieva; E. S. Tatarinova; E. V. Cherkasova; V. V. Medvedev

doi:10.1134/S0036023618070045

Synthesis and Crystal Structure of Tetrakis(dimethyl sulfoxide)copper(II) Hexafluorosilicate

作者: Cherkasova T.G.¹, Pervukhina N.V.², Kuratieva N.V.²^,3, Tatarinova E.S.¹, Cherkasova E.V.¹, Medvedev V.V.¹
隶属关系:
1. Kuzbass State Technical University
2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch
3. Novosibirsk National Research State University
期: 卷 63, 编号 7 (2018)
页面: 899-901
栏目: Coordination Compounds
URL: https://journal-vniispk.ru/0036-0236/article/view/168827
DOI: https://doi.org/10.1134/S0036023618070045
ID: 168827

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A new complex of composition [Cu(DMSO)₄SiF₆] (I), where DMSO is dimethyl sulfoxide (CH₃)₂SO, has been prepared and characterized by X-ray diffraction. Crystals I are triclinic, space group P\(\bar 1\), Z = 2, a = 10.1772(4) Å, b = 10.3061(5) Å, c = 10.6071(5) Å, V = 1003.94 Å3, ρ_calc = 1.714 g/cm³.