Email this article Identification of B−H···H−C Specific Interactions Observed in Complexes [M(solv)6][B10H10] (M = Co, Ni) by Spectral Analytical Methods
- Authors: Goeva L.V.1, Avdeeva V.V.1, Malinina E.A.1, Kuznetsov N.T.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 63, No 8 (2018)
- Pages: 1050-1055
- Section: Coordination Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/168902
- DOI: https://doi.org/10.1134/S0036023618080089
- ID: 168902
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Abstract
The B−H···H−C specific interactions observed in complexes [M(solv)6][B10H10], where M= Co(II), Ni(II); solv = DMF or DMSO, are analyzed based on the correlation between the X-ray diffraction data and the results of IR and UV spectroscopic studies. Comparing the experimental data obtained earlier with those reported here allows us to elucidate one of the reasons that do not permit unambiguously determine the presence of long-range contacts when interpreting spectral data.
About the authors
L. V. Goeva
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Russian Federation, Moscow, 119991
V. V. Avdeeva
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: avdeeva.varvara@mail.ru
Russian Federation, Moscow, 119991
E. A. Malinina
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Russian Federation, Moscow, 119991
N. T. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Russian Federation, Moscow, 119991
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