Email this article Synthesis and Structure of Bis(Ethylenediamine-N,N-Di-3-Propionato)Zinc Dihydrate
- Authors: Tsirul’nikova N.V.1, Dernovaya E.S.1, Volosneva O.N.2, Ananyev I.V.3, Belus S.K.1
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Affiliations:
- The Federal State Unitary Enterprise “Institute of Chemical Reagents and High Purity Chemical Substances of National Research Centre “Kurchatov Institute”
- Federal Research and Clinical Center of Physicochemical Medicine
- Nesmeyanov Institute of Organoelement Compounds
- Issue: Vol 63, No 10 (2018)
- Pages: 1322-1325
- Section: Coordination Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/169035
- DOI: https://doi.org/10.1134/S0036023618100194
- ID: 169035
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Abstract
Bis(ethylenediamine-N,N-di-3-propionato)zinc dihydrate [Zn(EDDP)]2 ∙ 2H2O is prepared from dichloro(ethylenediamine-N,N-di-3-propionato)zinc in the presence of silver(I) oxide. The prepared complex is studied by X-ray diffraction and spectroscopic methods. A molecule of the complex has a centrosymmetric dimeric structure. Zn atoms have trigonal-bipyramidal coordination formed by the nitrogen atoms of primary and tertiary amino groups, two oxygen atoms of propionic groups of one EDDP molecule, and one oxygen atom of the other.
About the authors
N. V. Tsirul’nikova
The Federal State Unitary Enterprise “Institute of Chemical Reagents and High Purity Chemical Substances of National Research Centre “Kurchatov Institute”
Author for correspondence.
Email: nv.tsir@mail.ru
Russian Federation, Moscow, 107076
E. S. Dernovaya
The Federal State Unitary Enterprise “Institute of Chemical Reagents and High Purity Chemical Substances of National Research Centre “Kurchatov Institute”
Email: nv.tsir@mail.ru
Russian Federation, Moscow, 107076
O. N. Volosneva
Federal Research and Clinical Center of Physicochemical Medicine
Email: nv.tsir@mail.ru
Russian Federation, Moscow, 119435
I. V. Ananyev
Nesmeyanov Institute of Organoelement Compounds
Email: nv.tsir@mail.ru
Russian Federation, Moscow, 119991
S. K. Belus
The Federal State Unitary Enterprise “Institute of Chemical Reagents and High Purity Chemical Substances of National Research Centre “Kurchatov Institute”
Email: nv.tsir@mail.ru
Russian Federation, Moscow, 107076
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