Nucleophilic Addition Reaction of Secondary Amines to Acetonitrilium closo-Decaborate [2-B10H9NCCH3]–
- Authors: Zhdanov A.P.1, Nelyubin A.V.1, Klyukin I.N.1, Selivanov N.A.1, Bortnikov E.O.1,2, Grigoriev M.S.3, Zhizhin K.Y.1, Kuznetsov N.T.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
- Mendeleev University of Chemical Technology, HCC Russian Academy of Sciences
- Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
- Issue: Vol 64, No 7 (2019)
- Pages: 841-846
- Section: Synthesis and Properties of Inorganic Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/169405
- DOI: https://doi.org/10.1134/S0036023619070180
- ID: 169405
Cite item
Abstract
The work is devoted to the study of the process of nucleophilic addition of secondary amines to a multiple bond of the nitrile derivative of the closo-decaborate anion (NBu4) [2-B10H9NCCH3]. The process results to the regioselective and stereoselective formation of disubstituted amidines. The process is carried out under mild conditions and allows functionalization of amines of various structure. The compounds obtained are characterized by multinuclear NMR spectroscopy, IR spectroscopy, elemental analysis. For the substances (NBu4)[2-B10H9(E-NH=C(N(CH2)5CH3)] and (NBu4)[2-B10H9(E-NH=C(N(C2H4)2O)] the structures were confirmed by X-ray diffraction.
Keywords
About the authors
A. P. Zhdanov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Author for correspondence.
Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991
A. V. Nelyubin
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991
I. N. Klyukin
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991
N. A. Selivanov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991
E. O. Bortnikov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Mendeleev University of Chemical Technology, HCC Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 125047
M. S. Grigoriev
Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119071
K. Yu. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991
N. T. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991
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