Nucleophilic Addition Reaction of Secondary Amines to Acetonitrilium closo-Decaborate [2-B10H9NCCH3]


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Abstract

The work is devoted to the study of the process of nucleophilic addition of secondary amines to a multiple bond of the nitrile derivative of the closo-decaborate anion (NBu4) [2-B10H9NCCH3]. The process results to the regioselective and stereoselective formation of disubstituted amidines. The process is carried out under mild conditions and allows functionalization of amines of various structure. The compounds obtained are characterized by multinuclear NMR spectroscopy, IR spectroscopy, elemental analysis. For the substances (NBu4)[2-B10H9(E-NH=C(N(CH2)5CH3)] and (NBu4)[2-B10H9(E-NH=C(N(C2H4)2O)] the structures were confirmed by X-ray diffraction.

About the authors

A. P. Zhdanov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

A. V. Nelyubin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

I. N. Klyukin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

N. A. Selivanov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

E. O. Bortnikov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Mendeleev University of Chemical Technology, HCC Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 125047

M. S. Grigoriev

Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119071

K. Yu. Zhizhin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

N. T. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Russian Federation, Moscow, 119991

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