Study of Hydrolysis Kinetic of New Laser Material [anti-B18H22]
- Авторлар: Chun-hua Tan 1, Zhang B.1, Chen J.1, Zhang L.1, Huang X.1, Meng H.1
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Мекемелер:
- Laboratory of Nanophotonic Functional Materials and Devices, School for Information and Optoelectronic Science and Engineering, South China Normal University
- Шығарылым: Том 64, № 11 (2019)
- Беттер: 1359-1364
- Бөлім: Synthesis and Properties of Inorganic Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/169543
- DOI: https://doi.org/10.1134/S0036023619110214
- ID: 169543
Дәйексөз келтіру
Аннотация
[anti-B18H22] is a potential blue laser material. In order to study the stability of [anti-B18H22] in aqueous solution, the hydrolytic reaction kinetic of [anti-B18H22] at various pH values and temperatures was studied by fluorescence spectroscopy. The results showed that [anti-B18H22] hydrolysis rate was accelerated by increasing temperature, and the trend showed that [anti-B18H22] hydrolyzed faster in low pH than in high pH solutions at the same temperature. The hydrolysis of [anti-B18H22] solution is second-order reaction at lower temperature (300.15–323.15 K), the activation energy is 52.37 kJ mol–1 and pre-exponential factor (A) is 7.9 × 1010. The work described here is significant for future studies of the properties of [anti-B18H22] in aqueous solution.
Негізгі сөздер
Авторлар туралы
Chun-hua Tan
Laboratory of Nanophotonic Functional Materials and Devices, School for Information and Optoelectronic Scienceand Engineering, South China Normal University
Хат алмасуға жауапты Автор.
Email: tch@scnu.edu.cn
ҚХР, Guangzhou, 510006
Bao-kai Zhang
Laboratory of Nanophotonic Functional Materials and Devices, School for Information and Optoelectronic Scienceand Engineering, South China Normal University
Email: tch@scnu.edu.cn
ҚХР, Guangzhou, 510006
Jie Chen
Laboratory of Nanophotonic Functional Materials and Devices, School for Information and Optoelectronic Scienceand Engineering, South China Normal University
Email: tch@scnu.edu.cn
ҚХР, Guangzhou, 510006
Lin-na Zhang
Laboratory of Nanophotonic Functional Materials and Devices, School for Information and Optoelectronic Scienceand Engineering, South China Normal University
Email: tch@scnu.edu.cn
ҚХР, Guangzhou, 510006
Xu-guang Huang
Laboratory of Nanophotonic Functional Materials and Devices, School for Information and Optoelectronic Scienceand Engineering, South China Normal University
Email: tch@scnu.edu.cn
ҚХР, Guangzhou, 510006
Hong-yun Meng
Laboratory of Nanophotonic Functional Materials and Devices, School for Information and Optoelectronic Scienceand Engineering, South China Normal University
Email: tch@scnu.edu.cn
ҚХР, Guangzhou, 510006
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