Thermal stability and products of decomposition of molybdenum(IV) complex with isopropylhydroxylamine [MoO 2 ( i -C 3 H 7 NHO) 2 ]

A. G. Beirakhov; E. G. Il’in; A. V. Rotov; E. A. Ugolkova; N. N. Efimov; V. V. Minin; A. E. Gekhman

doi:10.1134/S0036023616060036

Thermal stability and products of decomposition of molybdenum(IV) complex with isopropylhydroxylamine [MoO₂(i-C₃H₇NHO)₂]

Authors: Beirakhov A.G.¹, Il’in E.G.¹, Rotov A.V.¹, Ugolkova E.A.¹, Efimov N.N.¹, Minin V.V.¹, Gekhman A.E.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry
Issue: Vol 61, No 6 (2016)
Pages: 750-754
Section: Physical Methods of Investigation
URL: https://journal-vniispk.ru/0036-0236/article/view/166534
DOI: https://doi.org/10.1134/S0036023616060036
ID: 166534

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Abstract

The thermal behavior of the molybdenum(VI) complex with N-isopropylhydroxylamine [MoO₂(i-C₃H₇NHO)₂] has been studied. The thermal decomposition of the complex has been found to proceed in a single stage at 185.5°C and to result in non-stoichiometric molybdenum(IV) dioxide.