Synthesis and X-ray Crystallographic Study of [(UO2)2(C3H2O4)(Cl)2(C4H9NO)4]


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Аннотация

Crystals of [(UO2)2(mal)(Cl)2(DMA)4] (mal2– is malonate ion and DMA is dimethylacetamide) have been synthesized and studied by X-ray crystallography. The key structure units are binuclear island complexes [(UO2)2(mal)(Cl)2(DMA)4], which belong to the A2Q02M61 crystal-chemical group (A = UO22+, Q02 = mal2–, M1 = Cl and DMA) of uranyl complexes. The complexes form a framework through a system of intermolecular nonbonded interactions, which are characterized by means of the Voronoi–Direchlet molecular polyhedron method.

Авторлар туралы

Ya. Medvedkov

Samara National Research University Named after Academician S.P. Korolev

Email: lserezh@samsu.ru
Ресей, Samara, 443086

M. Grigor’ev

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: lserezh@samsu.ru
Ресей, Moscow, 119071

L. Serezhkina

Samara National Research University Named after Academician S.P. Korolev

Хат алмасуға жауапты Автор.
Email: lserezh@samsu.ru
Ресей, Samara, 443086

D. Pushkin

Samara National Research University Named after Academician S.P. Korolev

Email: lserezh@samsu.ru
Ресей, Samara, 443086

V. Serezhkin

Samara National Research University Named after Academician S.P. Korolev

Email: lserezh@samsu.ru
Ресей, Samara, 443086

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