Отправить статью по E-mail Tetraphenylantimony N-benzoylglycinate: synthesis and structure
- Авторы: Sharutin V.V.1, Sharutina O.K.1, Khnykina K.A.1
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Учреждения:
- South Ural State University (National Research University)
- Выпуск: Том 61, № 2 (2016)
- Страницы: 180-182
- Раздел: Coordination Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/167127
- DOI: https://doi.org/10.1134/S0036023616020194
- ID: 167127
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Аннотация
Tetraphenylantimony N-benzoylglycinate (I) has been synthesized by the reaction between pentaphenylantimony and N-benzoylglycine in toluene. According to X-ray diffraction data, the antimony atom in a molecule of complex I has a trigonal bipyramidal coordination to the oxygen atom in axial position. The Sb‒Ceq, Sb‒Cax, and Sb‒O bond lengths are 2.116(6)‒2.138(6), 2.183(6), and 2.200(4) Å, respectively. The intramolecular Sb⋯O=C distance between the carbonyl oxygen atom and the central antimony atom is 3.35(2) Å.
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Об авторах
V. Sharutin
South Ural State University (National Research University)
Автор, ответственный за переписку.
Email: vvsharutin@rambler.ru
Россия, pr. Lenina 76, Chelyabinsk, 454080
O. Sharutina
South Ural State University (National Research University)
Email: vvsharutin@rambler.ru
Россия, pr. Lenina 76, Chelyabinsk, 454080
K. Khnykina
South Ural State University (National Research University)
Email: vvsharutin@rambler.ru
Россия, pr. Lenina 76, Chelyabinsk, 454080
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