Email this article Paramagnetic properties of triple molybdates CsNa5M3(MoO4)6 (M = Ni, Co, Mn)
- Authors: Shkerin S.N.1, Uporov S.A.2, Yudin V.N.3, Solodovnikov S.F.3,4, Zolotova E.S.3, Tolkacheva A.S.1,5
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Affiliations:
- Institute of High-Temperature Electrochemistry, Ural Branch
- Institute of Metallurgy, Ural Branch
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- National Research Novosibirsk State University
- Institute of Materials Science and Metallurgy
- Issue: Vol 90, No 11 (2016)
- Pages: 2292-2296
- Section: Photochemistry and Magnetochemistry
- URL: https://journal-vniispk.ru/0036-0244/article/view/168992
- DOI: https://doi.org/10.1134/S0036024416110248
- ID: 168992
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Abstract
The static magnetization of CsNa5M3(MoO4)6 single phase molybdates, where M = Co, Ni, and Mn, is measured at 4–300 K in magnetic fields of up to 20 kOe. It is shown that the materials are paramagnetic. Magnetization as a function of temperature is described using the Curie–Weiss law. The intrinsic magnetic moments of the phases are found to be 9.759 (Co), 6.958 (Ni), and 12.203 Bohr magnetons for manganese molybdates. It is concluded that the charge state of Co, Ni, and Mn cations in the compounds is +2.
About the authors
S. N. Shkerin
Institute of High-Temperature Electrochemistry, Ural Branch
Author for correspondence.
Email: shkerin@mail.ru
Russian Federation, Yekaterinburg, 620137
S. A. Uporov
Institute of Metallurgy, Ural Branch
Email: shkerin@mail.ru
Russian Federation, Yekaterinburg, 620016
V. N. Yudin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: shkerin@mail.ru
Russian Federation, Novosibirsk, 630090
S. F. Solodovnikov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; National Research Novosibirsk State University
Email: shkerin@mail.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
E. S. Zolotova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: shkerin@mail.ru
Russian Federation, Novosibirsk, 630090
A. S. Tolkacheva
Institute of High-Temperature Electrochemistry, Ural Branch; Institute of Materials Science and Metallurgy
Email: shkerin@mail.ru
Russian Federation, Yekaterinburg, 620137; Yekaterinburg, 620083
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