Email this article Reduction of carbon dioxide by hydrogen on metal–carbon catalysts under supercritical conditions
- Authors: Bogdan V.I.1,2, Koklin A.E.1, Kozak D.O.1, Kustov L.M.1,2
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Affiliations:
- Zelinsky Institute of Organic Chemistry
- Department of Chemistry
- Issue: Vol 90, No 12 (2016)
- Pages: 2352-2357
- Section: Chemical Kinetics and Catalysis
- URL: https://journal-vniispk.ru/0036-0244/article/view/169014
- DOI: https://doi.org/10.1134/S0036024416120050
- ID: 169014
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Abstract
The reduction of carbon dioxide with hydrogen on metal–carbon (Ru, Rh, Ir) catalysts is investigated under supercritical conditions for the first time. High selectivity (close to 100%) toward methanation with good stability of catalytic activity is observed for Ru- and Rh-containing catalyst, while the preferred reduction to CO is observed for Ir/C catalyst.
About the authors
V. I. Bogdan
Zelinsky Institute of Organic Chemistry; Department of Chemistry
Email: lmk@ioc.ac.ru
Russian Federation, Moscow, 119991; Moscow, 119991
A. E. Koklin
Zelinsky Institute of Organic Chemistry
Email: lmk@ioc.ac.ru
Russian Federation, Moscow, 119991
D. O. Kozak
Zelinsky Institute of Organic Chemistry
Email: lmk@ioc.ac.ru
Russian Federation, Moscow, 119991
L. M. Kustov
Zelinsky Institute of Organic Chemistry; Department of Chemistry
Author for correspondence.
Email: lmk@ioc.ac.ru
Russian Federation, Moscow, 119991; Moscow, 119991
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