Email this article Reactivity of the CH-bonds of 2-butanol in liquid-phase oxidation
- Authors: Puchkov S.V.1, Nepomnyashchikh Y.V.1
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Affiliations:
- Kuzbass State Technical University
- Issue: Vol 91, No 12 (2017)
- Pages: 2337-2343
- Section: Chemical Kinetics and Catalysis
- URL: https://journal-vniispk.ru/0036-0244/article/view/169794
- DOI: https://doi.org/10.1134/S003602441712024X
- ID: 169794
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Abstract
The kinetics of product accumulation is studied in the azodiisobutyronitrile-initiated oxidation of 2-butanol. The relative reactivity for all types of the CH-bonds of 2-butanol is determined for reactions with peroxyl radicals at 60°C. It is established that the hydroxyl functional group of 2-butanol activates the CHbond in position 2 (α) and deactivates CH-bonds in positions 1, 3 (β), and 4 (γ), compared to the corresponding CH-bonds of saturated hydrocarbons.
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About the authors
S. V. Puchkov
Kuzbass State Technical University
Author for correspondence.
Email: psv.toos@kuzstu.ru
Russian Federation, Kemerovo, 650000
Yu. V. Nepomnyashchikh
Kuzbass State Technical University
Email: psv.toos@kuzstu.ru
Russian Federation, Kemerovo, 650000
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