Отправить статью по E-mail Rhodium Catalyst–Ionic Liquids Interaction by X-ray Photoelectron Spectroscopy Data
- Авторы: Yujuan Jin 1, Shuang Men 2
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Учреждения:
- School of Materials and Mechanical Engineering Beijing Technology and Business University
- School of Material Science and Engineering Shenyang Ligong University
- Выпуск: Том 92, № 12 (2018)
- Страницы: 2472-2475
- Раздел: Chemical Kinetics and Catalysis
- URL: https://journal-vniispk.ru/0036-0244/article/view/170251
- DOI: https://doi.org/10.1134/S0036024418120361
- ID: 170251
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Аннотация
We investigate the Schrock–Osborn catalyst, [Rh(COD)(PPh3)2][PF6], in a series of ionic liquids by XPS. The electronic environment of the rhodium centre is demonstrated. The subtle change of the electronic environment of the rhodium centre due to the catalyst-ionic liquids interaction is revealed based upon Rh 3d binding energy. It suggests that the anion of ionic liquids can have significant impact on the electronic environment of the rhodium centre.
Об авторах
Yujuan Jin
School of Materials and Mechanical Engineering Beijing Technology and Business University
Автор, ответственный за переписку.
Email: jinyujuan@th.btbu.edu.cn
Китай, Beijing
Shuang Men
School of Material Science and Engineering Shenyang Ligong University
Email: jinyujuan@th.btbu.edu.cn
Китай, Shenyang
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