Superparamagnetic and ferromagnetic behavior of ZnFe2O4 nanoparticles synthesized by microwave-assisted hydrothermal method

Resumo

Zinc ferrite (ZnFe₂O₄) nanoparticles were successfully synthesized from Zn(NO₃)₂ · 6H₂O and Fe(NO₃)₃ · 9H₂O by microwave hydrothermal method at 150°C for 1 h. Cubic ZnFe₂O₄ with particle size below 7 nm was formed in the solution at pH ≥ 6. The crystallinity and particle size of ZnFe₂O₄ nanoparticles were increased after calcination. The effects of pH of the precursor solution and calcination on the particle size and crystallinity of the particles were studied. At room temperature the products show superparamagnetic and ferromagnetic properties, determined by their size. The formation mechanism of ZnFe₂O₄ was also discussed according to the experimental results.