Oxidation of ethanol on NaX zeolite modified with transition metals
- Autores: Mirzai J.I.1, Nadirov P.A.1, Velieva A.D.1, Muradkhanli V.G.1
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Afiliações:
- Azerbaijan State Oil and Industrial University
- Edição: Volume 91, Nº 6 (2017)
- Páginas: 1005-1009
- Seção: Chemical Thermodynamics and Thermochemistry
- URL: https://journal-vniispk.ru/0036-0244/article/view/169517
- DOI: https://doi.org/10.1134/S0036024417060164
- ID: 169517
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Resumo
NaLaX, NaX + Co, and NaPdX catalysts are synthesized by modification of NaX zeolite with transition metals (La, Co, Pd). The activity of the prepared materials in catalytic ethanol oxidation is studied in the temperature range of 423–723 K. It is shown that NaPdX and NaX + Co accelerate the reactions of partial and complete oxidation of ethanol as the temperature rises. NaLaX accelerates both intramolecular and intermolecular dehydration of alcohol. It is shown that the NaPdX (1.0% Pd) sample has the highest activity in the complete oxidation of alcohol with the formation of CO2.
Sobre autores
J. Mirzai
Azerbaijan State Oil and Industrial University
Email: parviznadirov@rambler.ru
Azerbaijão, Baku, AZ100
P. Nadirov
Azerbaijan State Oil and Industrial University
Autor responsável pela correspondência
Email: parviznadirov@rambler.ru
Azerbaijão, Baku, AZ100
A. Velieva
Azerbaijan State Oil and Industrial University
Email: parviznadirov@rambler.ru
Azerbaijão, Baku, AZ100
V. Muradkhanli
Azerbaijan State Oil and Industrial University
Email: parviznadirov@rambler.ru
Azerbaijão, Baku, AZ100
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