Oxidation of ethanol on NaX zeolite modified with transition metals
- Авторы: Mirzai J.I.1, Nadirov P.A.1, Velieva A.D.1, Muradkhanli V.G.1
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Учреждения:
- Azerbaijan State Oil and Industrial University
- Выпуск: Том 91, № 6 (2017)
- Страницы: 1005-1009
- Раздел: Chemical Thermodynamics and Thermochemistry
- URL: https://journal-vniispk.ru/0036-0244/article/view/169517
- DOI: https://doi.org/10.1134/S0036024417060164
- ID: 169517
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Аннотация
NaLaX, NaX + Co, and NaPdX catalysts are synthesized by modification of NaX zeolite with transition metals (La, Co, Pd). The activity of the prepared materials in catalytic ethanol oxidation is studied in the temperature range of 423–723 K. It is shown that NaPdX and NaX + Co accelerate the reactions of partial and complete oxidation of ethanol as the temperature rises. NaLaX accelerates both intramolecular and intermolecular dehydration of alcohol. It is shown that the NaPdX (1.0% Pd) sample has the highest activity in the complete oxidation of alcohol with the formation of CO2.
Об авторах
J. Mirzai
Azerbaijan State Oil and Industrial University
Email: parviznadirov@rambler.ru
Азербайджан, Baku, AZ100
P. Nadirov
Azerbaijan State Oil and Industrial University
Автор, ответственный за переписку.
Email: parviznadirov@rambler.ru
Азербайджан, Baku, AZ100
A. Velieva
Azerbaijan State Oil and Industrial University
Email: parviznadirov@rambler.ru
Азербайджан, Baku, AZ100
V. Muradkhanli
Azerbaijan State Oil and Industrial University
Email: parviznadirov@rambler.ru
Азербайджан, Baku, AZ100
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