Redox potentials of uranium in molten eutectic mixture of lithium, potassium, and cesium chlorides


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Abstract

The behavior of uranium(III) and (IV) ions in the melts based on the eutectic mixture of lithium, potassium, and cesium chlorides has been studied using cyclic voltammetry in the range of 573–1073 K. The red-ox potentials of uranium have been determined and formal standard EU(III)/U(IV)* red-ox potentials have been calculated.

About the authors

D. S. Maltsev

Ural Federal University named after the First President of Russia B.N. Yeltsin

Email: v.a.volkovich@urfu.ru
Russian Federation, ul. Mira 19, Yekaterinburg, 620002

V. A. Volkovich

Ural Federal University named after the First President of Russia B.N. Yeltsin

Author for correspondence.
Email: v.a.volkovich@urfu.ru
Russian Federation, ul. Mira 19, Yekaterinburg, 620002

B. D. Vasin

Ural Federal University named after the First President of Russia B.N. Yeltsin

Email: v.a.volkovich@urfu.ru
Russian Federation, ul. Mira 19, Yekaterinburg, 620002

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