Corrosion of 12Kh18N10T Steel in the LiCl–KCl–nNdCl3 Melt


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Abstract

The high-temperature corrosion of a 12Kh18N10T steel in the melt of lithium and potassium chlorides and neodymium trichlorides is investigated at a temperature of 773 K. The NdCl3 concentration is varied from 0.2 to 5 mol %. In this study, neodymium is an analog of uranium. The composition of the electrolyte is close to the composition of the electrolytes used for processing nitride spent nuclear fuel (SNF). The main investigation technique is gravimetry, which includes aging of the steel in the melt for 1–24 h. Atomic absorption and electron microprobe analyses are also used.

About the authors

N. A. Kazakovtseva

Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences

Email: neekeetina@mail.ru
Russian Federation, Yekaterinburg, 620137

M. A. Maikov

Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University

Email: neekeetina@mail.ru
Russian Federation, Yekaterinburg, 620137; Yekaterinburg, 620002

E. V. Nikitina

Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University

Author for correspondence.
Email: neekeetina@mail.ru
Russian Federation, Yekaterinburg, 620137; Yekaterinburg, 620002

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