Mechanism and Caloric Effects of the Thermal Dehydration of GdCl3 ⋅ 6H2O Crystalline Hydrate
- Авторлар: Korzun I.V.1, Zakir’yanova I.D.1,2, Nikolaeva E.V.1,2
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Мекемелер:
- Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
- Ural Federal University
- Шығарылым: Том 2018, № 8 (2018)
- Беттер: 722-727
- Бөлім: Article
- URL: https://journal-vniispk.ru/0036-0295/article/view/172033
- DOI: https://doi.org/10.1134/S0036029518080104
- ID: 172033
Дәйексөз келтіру
Аннотация
Abstract—The thermal dehydration of GdCl3 ⋅ 6H2O crystalline hydrate is studied by synchronous thermal analysis and mass spectrometry using certified samples. The mechanism and the caloric effects of the chemical reactions are determined. The thermal decomposition of GdCl3 ⋅ 6H2O crystalline hydrate is accompanied by hydrolysis, leading to the formation of oxychloride GdOCl.
Авторлар туралы
I. Korzun
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
Email: optica96@ihte.uran.ru
Ресей, Yekaterinburg, 620000
I. Zakir’yanova
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University
Хат алмасуға жауапты Автор.
Email: optica96@ihte.uran.ru
Ресей, Yekaterinburg, 620000; Yekaterinburg, 620002
E. Nikolaeva
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University
Email: optica96@ihte.uran.ru
Ресей, Yekaterinburg, 620000; Yekaterinburg, 620002
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