Mechanism and Caloric Effects of the Thermal Dehydration of GdCl3 ⋅ 6H2O Crystalline Hydrate


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Abstract—The thermal dehydration of GdCl3 ⋅ 6H2O crystalline hydrate is studied by synchronous thermal analysis and mass spectrometry using certified samples. The mechanism and the caloric effects of the chemical reactions are determined. The thermal decomposition of GdCl3 ⋅ 6H2O crystalline hydrate is accompanied by hydrolysis, leading to the formation of oxychloride GdOCl.

Авторлар туралы

I. Korzun

Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences

Email: optica96@ihte.uran.ru
Ресей, Yekaterinburg, 620000

I. Zakir’yanova

Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University

Хат алмасуға жауапты Автор.
Email: optica96@ihte.uran.ru
Ресей, Yekaterinburg, 620000; Yekaterinburg, 620002

E. Nikolaeva

Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University

Email: optica96@ihte.uran.ru
Ресей, Yekaterinburg, 620000; Yekaterinburg, 620002

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