Отправить статью по E-mail Mechanism and Caloric Effects of the Thermal Dehydration of GdCl3 ⋅ 6H2O Crystalline Hydrate
- Авторы: Korzun I.V.1, Zakir’yanova I.D.1,2, Nikolaeva E.V.1,2
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Учреждения:
- Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
- Ural Federal University
- Выпуск: Том 2018, № 8 (2018)
- Страницы: 722-727
- Раздел: Article
- URL: https://journal-vniispk.ru/0036-0295/article/view/172033
- DOI: https://doi.org/10.1134/S0036029518080104
- ID: 172033
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Аннотация
Abstract—The thermal dehydration of GdCl3 ⋅ 6H2O crystalline hydrate is studied by synchronous thermal analysis and mass spectrometry using certified samples. The mechanism and the caloric effects of the chemical reactions are determined. The thermal decomposition of GdCl3 ⋅ 6H2O crystalline hydrate is accompanied by hydrolysis, leading to the formation of oxychloride GdOCl.
Об авторах
I. Korzun
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
Email: optica96@ihte.uran.ru
Россия, Yekaterinburg, 620000
I. Zakir’yanova
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University
Автор, ответственный за переписку.
Email: optica96@ihte.uran.ru
Россия, Yekaterinburg, 620000; Yekaterinburg, 620002
E. Nikolaeva
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University
Email: optica96@ihte.uran.ru
Россия, Yekaterinburg, 620000; Yekaterinburg, 620002
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