Кристаллизация газонасыщенных слоев аморфного льда с зародышевыми кристаллами
- Авторлар: Faizullin M.Z.1, Vinogradov A.V.1, Tomin A.S.1, Koverda V.P.1, Bryukhanov V.M.1
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Мекемелер:
- Institute of Thermophysics Ural Branch of the Russian Academy of Sciences
- Шығарылым: Том 63, № 1 (2025)
- Беттер: 85-90
- Бөлім: Heat and Mass Transfer and Physical Gasdynamics
- URL: https://journal-vniispk.ru/0040-3644/article/view/320072
- DOI: https://doi.org/10.31857/S0040364425010137
- ID: 320072
Дәйексөз келтіру
Аннотация
Experimental investigation of the spontaneous crystallization of gas-saturated layers of amorphous ice obtained by low-temperature condensation of supersonic streams of rarefied vapor and ethane at various orientations relative to the cooled substrate has been conducted. The presence of crystalline embryos formed in the supersonic vapor flow in a nonequilibrium medium provides conditions for initiating "hot" centers and the transition to spontaneous crystallization of the gas-saturated layer with the formation of gas hydrate. The obtained samples contained a high gas concentration significantly exceeding that for ethane hydrate in equilibrium. The high gas saturation indicates the presence of gas molecules in the porous medium of the condensate in a free state.
Авторлар туралы
M. Faizullin
Institute of Thermophysics Ural Branch of the Russian Academy of Sciences
Email: faizullin@itp.uran.ru
Yekaterinburg, Russia
A. Vinogradov
Institute of Thermophysics Ural Branch of the Russian Academy of Sciences
Email: faizullin@itp.uran.ru
Yekaterinburg, Russia
A. Tomin
Institute of Thermophysics Ural Branch of the Russian Academy of Sciences
Email: faizullin@itp.uran.ru
Yekaterinburg, Russia
V. Koverda
Institute of Thermophysics Ural Branch of the Russian Academy of Sciences
Email: faizullin@itp.uran.ru
Yekaterinburg, Russia
V. Bryukhanov
Institute of Thermophysics Ural Branch of the Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: faizullin@itp.uran.ru
Yekaterinburg, Russia
Әдебиет тізімі
- Mishima O. Reversible First-order Transition between Two H2O Amorphs at ~0.2 GPa and ~135 K // J. Chem. Phys. 1994. V. 100. № 8. P. 5910.
- Loerting T., Salzmann C., Kohl I., Mayer E., Hallbrucker A. A Second Distinct Structural “State” of High-density Amorphous Ice at 77 K and 1 bar // Phys. Chem. Chem. Phys. 2001. № 3. P. 5355.
- Loerting T., Winkel K., Seidl M., Bauer M., Mitterdorfer C., Handle P.H., Salzmann C.G., Mayer E., Finneyd J.L., Bowron D.T. How Many Amorphous Ices Are There? // Phys. Chem. Chem. Phys. 2011. № 13. P. 8783.
- Tonauer C.M., Fidler L.-R., Giebelmann J., Yama- shita K., Loerting T. Nucleation and Growth of Crystalline Ices from Amorphous Ices // J. Chem. Phys. 2023. V. 158. 141001.
- Stevenson K.P., Kimmel G.A., Dohnalek Z., Scott Smith R., Kay B.D. Controlling the Morphology of Amorphous Solid Water // Science. 1999. V. 283. P. 1505.
- Kimmel G.A., Stevenson K.P., Dohnalek Z., Scott Smith R., Kay B.D. Control of Amorphous Solid Water Morpho- logy Using Molecular Beams. I. Experimental Results // J. Chem. Phys. 2001. V. 114. № 12. P. 5284.
- Faizullin M.Z., Vinogradov A.V., Tomin A.S., Koverda V.P. Nonstationary Nucleation (Explosive Crystallization) in Layers of Amorphous Ice Prepared by Low-temperature Condensation of Supersonic Molecular Beams // Int. J. Heat Mass Transfer. 2017. V. 108. P. 1292.
- Файзуллин М.З., Виноградов А.В., Томин А.С., Коверда В.П. Исследование процессов конденсации и кристаллизации при образовании газовых гидратов в сверхзвуковых струях // ТВТ. 2019. Т. 57. № 5. С. 769.
- Faizullin M.Z., Vinogradov A.V., Koverda V.P. Hydrate Formation in Layers of Gas-saturated Amorphous Ice // Chem. Eng. Sci. 2015. V. 130. P. 135.
- Sloan E.D., Koh C.A. Clathrate Hydrates of Natural Gases. 3rd ed. Boca Raton: CRC Press, 2007. 752 p.
- Kvendolden K. Gas Hydrates–Geological Perspective and Global Change // Rev. Geophys. 1993. V. 31. № 2. P. 173.
- Hag B.U. Gas Hydrates: Greenhouse Nightmare? Energy Panacea or Pipe Dream? // GSA Today. 1998. V. 8. № 11. P. 1.
- Чернов А.А. Процессы кристаллизации. В кн.: Современная кристаллография. Т. 3. М.: Наука, 1980. С. 162.
- Suga H., Seki S. Thermodynamic Investigation on Glassy States of Pure Simple Compounds // J. Non-Cryst. Solids. 1974. V. 16. № 2. P. 171.
- Ghormley J.A. Enthalpy Changes and Heat-capacity Changes in the Transformations from High-surface- area Amorphous Ice to Stable Hexagonal Ice // J. Chem. Phys. 1968. V. 48. № 7. P. 503.
- Файзуллин М.З., Виноградов А.В., Коверда В.П. Свойства газовых гидратов, полученных неравновесной конденсацией молекулярных пучков // ТВТ. 2014. Т. 52. № 6. С. 852.
- Uhlmann D.R. A Kinetic Treatment of Glass Formation // J. Non-Cryst. Solids. 1972. V. 7. № 2. P. 337.
- Faizullin M.Z., Skokov V.N., Koverda V.P. Glass Transition and Crystallization of Water and Aqueous Solutions of Organic Liquids // J. Non-Cryst. Solids. 2010. V. 356. № 23–24. P. 1153.
- Torchet G., Schwartz J., Farges J., de Feraudy M.F., Raoult B. Structure of Solid Water Formed in a Free Jet Expansion // J. Chem. Phys. 1983. V. 79. № 12. P. 6196.
- Yakushev V.S., Istomin V.A. Gas Hydrate Self-preservation Effect. In: Physics and Chemistry of Ice / Eds. Maeno N., Hondoh T. Sapporo: Hokkaido Univ. Press, 1992. P. 136.
- Stern L.A., Circone S., Kirby S.H., Durham W.B. Ano-malous Preservation of Pure Methane Hydrate at 1 atm // J. Phys. Chem. B. 2021. V. 105. P. 1756.
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