Selective Sorbents Based on 2-Hydroxyethylmethacrylate and Ethylene Glycol Dimethacrylate Modified with Boric Acid as High-Affinity Ligands for Glucose

I. S. Garkushina; Гаркушина И. С.; A. S. Panyuta; Панюта А. С.; P. Yu. Morozova; Морозова П. Ю.; A. A. Osipenko; Осипенко А. А.

doi:10.31857/S0044185623700614

Selective Sorbents Based on 2-Hydroxyethylmethacrylate and Ethylene Glycol Dimethacrylate Modified with Boric Acid as High-Affinity Ligands for Glucose

Autores: Garkushina I.S.¹, Panyuta A.S.², Morozova P.Y.², Osipenko A.A.²
Afiliações:
1. Institute of Macromolecular Compounds, Russian Academy of SciencesInstitute of Macromolecular Compounds, Russian Academy of Sciences
2. Institute of Macromolecular Compounds, Russian Academy of Sciences
Edição: Volume 59, Nº 5 (2023)
Páginas: 506-516
Seção: ФИЗИКО-ХИМИЧЕСКИЕ ПРОЦЕССЫ НА МЕЖФАЗНЫХ ГРАНИЦАХ
URL: https://journal-vniispk.ru/0044-1856/article/view/139765
DOI: https://doi.org/10.31857/S0044185623700614
EDN: https://elibrary.ru/VFENJM
ID: 139765

Citar

Texto integral

Acesso aberto
Acesso é fechado

Acesso está concedido
Acesso é fechado

Somente assinantes

Resumo
Sobre autores
Bibliografia
Arquivos suplementares
Estatísticas

Resumo

A synthesis method of granulated polymeric sorbents based on 2-hydroxyethylmethacrylate and ethylene glycol dimethacrylate that possess affinity to glucose sorption sites formed by boric acid molecules has been developed. The participation of boric acid as an additional crosslinking agent and the effect of the amount of the introduced ligand on the surface morphology of the granules and physicochemical properties of the polymeric sorbents have been determined. It has been found that this modification of the polymer matrix promotes an increase in the affinity of the sorption surface and its adsorption capacity to bind glucose in a dynamic mode, as well as high selectivity in comparison with the sorption of its structural analogue, fructose. This can further be used in the development of a method of isolation of glucose from a multicomponent solution and a sorption method of separation of sugars.

Bibliografia

Ning H. et al. // J. Chromatogr. A. 2022. V. 1671. P. 462994.
Hasanah A.N. et al. // J. Chem. Hindawi Limited. 2020. V. 2020. ID 7282415
Tu X. et al. // Talanta. 2021. V. 226. P. 122142.
Alipour S. et al. // J. Mater. Res. Technol. 2021. V. 12. P. 2298–2306.
Eivazzadeh-Keihan R. et al. // TrAC Trends Anal. Chem. 2021. V. 141. P. 116291.
Xu R. et al. // J. Chromatogr. A. 2021. V. 1635. P. 461707.
Hu Z., Wang X., Chen X. // Anal. Chim. Acta. 2020. V. 1112. P. 16–23.
Gheybalizadeh H., Hejazi P. // React. Funct. Polym. 2022. V. 171. P. 105152.
Amorim M.S., Sales M.G.F., Frasco M.F. // Biosens. Bioelectron. 2022. V. 10. P. 100131.
Li M. et al. // Kexue Tongbao/Chinese Science Bulletin. 2019. V. 64. № 13. P. 1321–1329.
Askin S., Kizil S., Bulbul Sonmez H. // React. Funct. Polym. 2021. V. 167. P. 105002.
Bayraktaroglu S., Kizil S., Bulbul Sonmez H. // J. Environ. Chem. Eng. 2021. V. 9. № 5. P. 106002.
Sulejmanović J. et al. // Chemosphere. 2022. V. 296. P. 133971.
Wang H.H., Shyr T.W., Hu M.S. // J. Appl. Polym. Sci. 1999. V. 74. № 13. P. 3046–3052.
Prosanov I.Y. et al. // Mater. Today Commun. 2018. V. 14. P. 77–81.
Hong X. et al. // J. Appl. Polym. Sci. 2021. V. 138. № 47.
Vedelago J. et al. // Sci. Reports. 2021. V. 11. № 1. P. 1–14.
Belcher R., Tully G.W., Svehla G. // Anal. Chim. Acta. 1970. V. 50. № 2. P. 261–267.
Dawber J.G., Matusin D.H. // J. Chem. Soc. Faraday Trans. 1982. V. 78. № 8. P. 2521–2528.
Crabb W.D., Mitchinson C. // Trends Biotechnol. 1997. V. 15. № 9. P. 349–352.
Kuznetsov B.N. et al. // Катализ в промышленности. 2017. V. 17. № 6. P. 543–553. (In Russ.).
Dupont H. et al. // Macromolecules. 2021. V. 54. № 11. P. 4945–4970.
Yang Y. et al. // Frontiers in Pharmacology. 2017. V. 8. № MAY. P. 287.
Willaman J.J., Davison F.R. // J. Agric. Res. 1924. V. 28. № 5. P. 479–487.
Umpleby R.J. et al. // Journal of Chromatography B: Analytical Technologies in the Biomedical and Life Sciences. 2004. V. 804. № 1. P. 141–149.
Hinz C. // Geoderma. 2001. V. 99. № 3–4. P. 225–243.
Freundlich H. // Zeitschrift für Phys. Chemie. 1907. V. 57U. № 1. P. 385–470.
Ebadi A., Soltan Mohammadzadeh J.S., Khudiev A. // Adsorption. 2009. V. 15. № 1. P. 65–73.
Ebadi A., Soltan Mohammadzadeh J.S., Khudiev A. // Chem. Eng. Technol. 2007. V. 30. № 12. P. 1666–1673.
Krishna Kumar A.S., Jiang S.J., Tseng W.L. // J. Mater. Chem. A. 2015. V. 3. № 13. P. 7044–7057.
Malarvizhi R., Sulochana N. // J. Environ. Prot. Sci. 2008. V. 2. P. 40–46.
Liu Y. // Colloids Surfaces A Physicochem. Eng. Asp. 2006. V. 274. № 1–3. P. 34–36.
Giles C.H., Smith D., Huitson A. // J. Colloid Interface Sci. 1974. V. 47. № 3. P. 755–765.
Boyd G.E., Adamson A.W., Myers L.S. // J. Am. Chem. Soc. 1947. V. 69. № 11. P. 2836–2848.
Lagergren S. // Springer-Verlag. 1907. V. 2. № 1. P. 15.