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Thermochemistry of the Dissolution of Tetra-4-carboxymetallophthalocyanines in Aqueous Solutions of KOH at 298.15 K
- Authors: Krutova O.N.1, Maizlish V.E.1, Lytkin A.I.1, Chernikov V.V.1, Volkov A.V.1, Fedotova A.E.1, Krutov P.D.1
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Affiliations:
- Ivanovo State University of Chemistry and Technology
- Issue: Vol 97, No 2 (2023)
- Pages: 199-203
- Section: ХИМИЧЕСКАЯ ТЕРМОДИНАМИКА И ТЕРМОХИМИЯ
- Submitted: 15.10.2023
- Published: 01.02.2023
- URL: https://journal-vniispk.ru/0044-4537/article/view/136503
- DOI: https://doi.org/10.31857/S0044453723020115
- EDN: https://elibrary.ru/ECUSCJ
- ID: 136503
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Abstract
Complexes are obtained of tetra-4-carboxyphthalocyanines with copper and zinc that are insoluble in water. Standard enthalpies of formation of the compounds are calculated according to additive groups based on group systematics with a Benson-type classification of fragments that considers the influence of the primary environment of atoms. Thermal effects of the dissolution of crystalline tetra-4-carboxymetallo-phthalocyanines in aqueous solutions at different concentrations of KOH (0.002 to 0.02 mol/L) at 298.15 K are determined via direct calorimetry. The standard enthalpies of formation are calculated for products of the dissociation of complexes of tetra-4-carboxyphthalocyanines with copper and zinc in aqueous solutions.
About the authors
O. N. Krutova
Ivanovo State University of Chemistry and Technology
Email: kdvkonkpd@yandex.ru
153000, Ivanovo, Russia
V. E. Maizlish
Ivanovo State University of Chemistry and Technology
Email: kdvkonkpd@yandex.ru
153000, Ivanovo, Russia
A. I. Lytkin
Ivanovo State University of Chemistry and Technology
Email: kdvkonkpd@yandex.ru
153000, Ivanovo, Russia
V. V. Chernikov
Ivanovo State University of Chemistry and Technology
Email: kdvkonkpd@yandex.ru
153000, Ivanovo, Russia
A. V. Volkov
Ivanovo State University of Chemistry and Technology
Email: kdvkonkpd@yandex.ru
153000, Ivanovo, Russia
A. E. Fedotova
Ivanovo State University of Chemistry and Technology
Email: kdvkonkpd@yandex.ru
153000, Ivanovo, Russia
P. D. Krutov
Ivanovo State University of Chemistry and Technology
Author for correspondence.
Email: kdvkonkpd@yandex.ru
153000, Ivanovo, Russia
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