Synthesis of Graphdiynes, Morphological Study, and Comparative Analysis of the Hydrogen Adsorption Properties of Graphenes and Graphdiynes

A. P. Soldatov; Солдатов А. П.; A. D. Budnyak; Будняк А. Д.; A. N. Kirichenko; Кириченко А. Н.; A. M. Ilolov; Илолов А. М.

doi:10.31857/S0044453723100229

Synthesis of Graphdiynes, Morphological Study, and Comparative Analysis of the Hydrogen Adsorption Properties of Graphenes and Graphdiynes

Authors: Soldatov A.P.¹, Budnyak A.D.¹, Kirichenko A.N.², Ilolov A.M.¹
Affiliations:
1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
2. Private Institution of the State Atomic Energy Corporation Rosatom ITER Project Center
Issue: Vol 97, No 10 (2023)
Pages: 1457-1463
Section: ФИЗИЧЕСКАЯ ХИМИЯ НАНОКЛАСТЕРОВ, СУПРАМОЛЕКУЛЯРНЫХ СТРУКТУР И НАНОМАТЕРИАЛОВ
Submitted: 18.10.2023
Published: 01.10.2023
URL: https://journal-vniispk.ru/0044-4537/article/view/140329
DOI: https://doi.org/10.31857/S0044453723100229
EDN: https://elibrary.ru/PNXVFH
ID: 140329

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Abstract
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Abstract

Graphdiynes (GDYs) are two-dimensional carbon nanostructures containing sp- and sp2-hybridized carbon atoms that form conjugated bonds in the linear chains connecting six-membered carbon rings. The results of scanning and transmission electron microscopy (SEM and TEM), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy showed that GDYs have a uniform surface and contain conjugated –С≡С–С≡С bonds. The hydrogen-adsorption capacity of GDYs was studied, and a comparative analysis of hydrogen adsorption in GDYs, graphenes, graphene nanotubes, and graphene structures formed on zeolites was performed. The substrate on which the carbon nanostructure is formed was shown to have a significant effect on the adsorption capacity of the latter. The possibility and prospects for the synthesis of graphenes on catalysts to increase their efficiency in hydrogenation processes are considered.

Keywords

graphdiyne nanostructures, synthesis of nanosized graphdiynes (GDYs), study of their morphology, structure of graphdiyne, acetylene bonds in GDY, hydrogen adsorption in carbon nanostructures, influence of morphology and substrate

References

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