Electrochemical Properties of N-Methyl-2,2'-bipyridinium Iodide and N,N'-Dimethyl-2,2'-bipyridinium Iodide

A. V. Dolganov; Долганов А. В.; L. A. Klimaeva; Климаева Л. А.; E. E. Muryumin; Мурюмин Е. Е.; S. G. Kostryukov; Кострюков С. Г.; A. Sh. Kozlov; Козлов А. Ш.; O. V. Tarasova; Тарасова О. В.; A. V. Knyazev; Князев А. В.

doi:10.31857/S0044453723100060

Electrochemical Properties of N-Methyl-2,2'-bipyridinium Iodide and N,N'-Dimethyl-2,2'-bipyridinium Iodide

Authors: Dolganov A.V.¹, Klimaeva L.A.¹, Muryumin E.E.¹, Kostryukov S.G.¹, Kozlov A.S.¹, Tarasova O.V.¹, Knyazev A.V.²
Affiliations:
1. Mordovia State University
2. Lobachevsky State University of Nizhny Novgorod
Issue: Vol 97, No 10 (2023)
Pages: 1502-1509
Section: ЭЛЕКТРОХИМИЯ. ГЕНЕРАЦИЯ И АККУМУЛИРОВАНИЕ ЭНЕРГИИ ИЗ ВОЗОБНОВЛЯЕМЫХ ИСТОЧНИКОВ
Submitted: 18.10.2023
Published: 01.10.2023
URL: https://journal-vniispk.ru/0044-4537/article/view/140335
DOI: https://doi.org/10.31857/S0044453723100060
EDN: https://elibrary.ru/IIAXBR
ID: 140335

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Abstract
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Abstract

The electrochemical properties of N-substituted salts of 2,2'-bipyridine: N-methyl-2,2'-bipyridinium iodide and N,N '-dimethyl-2,2'-bipyridinium iodide were studied by cyclic voltammetry (CV). The electrochemical properties are greatly affected by the methyl substituents at the nitrogen atom in the ortho-bipyridine molecule. The conproportionation constants were calculated for N,N '-dimethyl-2,2'-bipyridinium iodide and made it possible to judge about the degree of electron localization in the systems.

Keywords

2,2'-bipyridine, electrochemical properties, cyclic voltammetry

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