SULFONIUM DERIVATIVES OF closo-DECABORATE ANION WITH CARBONYL GROUPS

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Abstract

The paper presents the synthesis of sulfonium derivatives of the closo-decaborate anion with exo-polyhedral carbonyl groups [B10H9S(CH2C(=O)R)2]- (R = Me, Ph, p-C6H4C1, Nh). The composition and structure are confirmed by elemental analysis, 11B, 1H, and 13C NMR spectroscopy. Crystal packings and intermolecular interactions for the compounds Bu4N[2-BwH9S(CH2COMe)2] and [Ag(FFh3)4][2-B10H9S(CH2COC6H4Cl)2] are studied using X-ray structural analysis and Hirschfeld surface analysis of the anions.

About the authors

A. S Kubasov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: fobosax@mail.ru
Moscow, Russia

A. V Golubev

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

O. M Stepanova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

P. Yu Zhizhin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

N. T Kuznetsova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

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