SYNTHESIS OF HIGH ELECTROCONDUCTIVE ZnO/CNT NANOCOMPOSITES WITH CHEMORESISTIVE RESPONSE AT ROOM TEMPERATURE

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Abstract

ZnO/CNT nanocomposites with CNT content from 0.01 to 10 wt.% were prepared using solvothermal synthesis. The thermal behavior of the obtained composites was studied at heating up to 850℃ using DSC/TGA. The phase composition was studied using XRD and Raman spectroscopy and the formation of hexagonal wurtzite phase was established. According to SEM data, zinc oxide nanoparticles are localized on the CNT surface. The temperature dependence of electrical resistance of ZnO/CNT nanocomposites was studied. It is shown that semiconductor or metallic type of conductivity is observed depending on the CNT content. The chemoresistive responses to a wide range of gases were studied at room temperature, the best sensitivity was shown by the sample with the lowest CNT content (0.01 wt. %).

About the authors

A. S Mokrushin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: artyom.nano@gmail.com
Moscow, Russia

S. A Dmitrieva

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; D.I. Mendeleev Russian University of Chemical Technology

Moscow, Russia

I. A Nagornov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

N. P Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

A. M Vorobei

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

A. A Averin

A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Moscow, Russia

E. P Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

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