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N-Sulfinyltrifluoromethanesulfonamide in [4+2]-Cycloaddition Reactions
- Authors: Tolstikova L.L1, Astakhova V.V1, Moskalik M.Y.1
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Affiliations:
- Federal Research Center "Irkutsk Institute of Chemistry named after A.E. Favorsky", Siberian Branch of the Russian Academy of Sciences
- Issue: Vol 95, No 11-12 (2025)
- Pages: 554-561
- Section: Articles
- URL: https://journal-vniispk.ru/0044-460X/article/view/362181
- DOI: https://doi.org/10.7868/S3034559625110108
- ID: 362181
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Abstract
The reaction of N-sulfinyltrifluoromethanesulfonamide with acyclic conjugated dienes in methylene chloride was shown to afford the corresponding cycloadducts in high yields. Methyl vinyl ketone reacted with N-sulfinyltrifluoromethanesulfonamide in the presence of thionyl chloride, also affording the cycloaddition product, while terminal alkenes in this reaction give the corresponding sulfinamides.
About the authors
L. L Tolstikova
Federal Research Center "Irkutsk Institute of Chemistry named after A.E. Favorsky", Siberian Branch of the Russian Academy of Sciences
ORCID iD: 0000-0002-0530-7429
V. V Astakhova
Federal Research Center "Irkutsk Institute of Chemistry named after A.E. Favorsky", Siberian Branch of the Russian Academy of Sciences
Email: astakhova_vera@irioch.irk.ru
ORCID iD: 0000-0001-9716-6004
M. Yu Moskalik
Federal Research Center "Irkutsk Institute of Chemistry named after A.E. Favorsky", Siberian Branch of the Russian Academy of Sciences
ORCID iD: 0000-0002-9460-3413
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