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Extraction of Lanthanides(III) from Nitric Acid Solutions with Complexes of Biscarbamoylmethylphosphine Oxides with Bis[(trifluoromethyl)sulfonyl]imide
- Authors: Turanov A.N1, Karandashev V.K2, Khvostikov V.A2
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Affiliations:
- Osipyan Institute of Solid State Physics of the Russian Academy of Sciences
- Institute of Microelectronics Technology and High Purity Materials of the Russian Academy of Sciences
- Issue: Vol 95, No 11-12 (2025)
- Pages: 579–585
- Section: Articles
- URL: https://journal-vniispk.ru/0044-460X/article/view/362184
- DOI: https://doi.org/10.7868/S3034559625110137
- ID: 362184
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Abstract
The extraction of lanthanides(III) with solutions of biscarbamoylmethylphosphine oxide complexes with bis[(trifluoromethyl)sulfonyl]imide (HTf2N) was studied. It was found that lanthanide(III) ions are extracted from nitric acid solutions with solutions of such complexes by the cation exchange mechanism. The stoichiometry of the extracted lanthanide(III) complexes was determined, the influence of the structure of biscarbamoylmethylphosphine oxides, the nature of the organic solvent and the concentration of HNO3 in the aqueous phase on the efficiency of metal ion extraction into the organic phase was considered. It was found that the conversion of bis-CMPO into complexes with HTf2N leads to an increase in the extraction of lanthanide(III) ions from nitric acid solutions.
About the authors
A. N Turanov
Osipyan Institute of Solid State Physics of the Russian Academy of Sciences
ORCID iD: 0000-0002-5064-191X
Chernogolovka, Russia
V. K Karandashev
Institute of Microelectronics Technology and High Purity Materials of the Russian Academy of Sciences
Email: karan@iptm.ru
ORCID iD: 0000-0003-0684-272X
Chernogolovka, Russia
V. A Khvostikov
Institute of Microelectronics Technology and High Purity Materials of the Russian Academy of Sciences
ORCID iD: 0000-0002-2543-6842
Chernogolovka, Russia
References
- Myasoedov B.F., Kalmykov S.N. // Mendeleev Commun. 2015. Vol. 25. N 5. P. 319. doi: 10.10016/j.mencom.2015.09.001
- Horwitz E.P., Martin K.A., Diamond H., Kaplan L. // Solvent Extr. Ion Exch. 1986. Vol. 4. № 3. P. 449. doi: 10.1080/07366298608917877
- Чмутова М.К., Липениа М.Н., Прибылова Г.А., Иванова Л.А., Смирнов И.В., Шадрин А.Ю., Мясоедов Б.Ф. // Радиохимия. 1999. Т. 41. № 4. С. 331.
- Alyapyshev M.Yu., Babain V.A., Ustynюuk Yu.A. // Russ. Chem. Rev. 2016. Vol. 85. N 9. P. 943. doi: 10.1070/RCR4588
- Turanov A.N., Karandashev V.K., Yarkevich A.N. // Radiochemistry. 2021. Vol. 63. P. 454. doi: 10.1134/S1066362221040081
- Riano S., Foltova S.S., Binnemans K. // RSC Adv. 2020. Vol. 10. P. 307. doi: 10.1039/c9ra08996
- Raut D.R., Sharma S., Ghosh S.K., Mohapatra P.K. // Sep. Sci. Technol. 2017. Vol. 52. P. 1430. doi: 10.1080/01496395.2017.1290112
- Iqbal M., Waheed K., Rahat S.B., Mehmood T., Lee M.S. // J. Radioanal. Nucl. Chem. 2020. Vol. 325. P. 1. doi: 10.1007/s10967-020-07199-1
- Mohapatra P.K. // Chem. Prod. Proc. Model. 2015. Vol. 10. P. 135. doi: 10.1515/cppm-2014-0030
- Белова В.В. // Радиохимия. 2021. Т. 63. С. 3; Belova V.V. // Radiochemistry. 2021. Vol. 63. P. 1. doi: 10.1134/S106636222101001X
- Quijada-Maldonado E., Olea F., Supulveda R., Castillo J., Cabezos R., Merlet G., Romero J. // Sep. Pur. Technol. 2020. Vol. 251. 117289. doi: 10.1016/j.seppur.2020.117289
- Wang K., Adidharma H., Radosz M., Wan P., Xu X., Russell C.K., Tian H., Fan M., Yu J. // Green Chem. 2017. Vol. 19. P. 4469. doi: 10.1039/c7gc02141k
- Atanassova M. // J. Mol. Liq. 2021. Vol. 343. Art. 117530. doi ????
- Turanov A.N., Karandashev V.K., Yarkevich A.N. // Radiochemistry. 2022. Vol. 64. N 2. P. 163. doi: 10.1134/S106636222020072
- Gerasimov M.A., Pozdeev A.V., Evsinnina M.V., Kalle P., Yarenkov N.R., Borisova N.E., Manveev P.I. // Inorg. Chem. 2025. Vol. 63. P. 2109. doi: 10.1021/acs.inorgchem.3c03944
- Diò N., Dario Falcone R., Acuna A., Garcia-Rio L. // J. Mol. Liq. 2020. Vol. 304. 112762. doi: 10.1016/j.molliq.2020.112762
- Gaillard C., Boltoeva M., Billard I., Georg S., Mazan V., Ouadi A., Ternova D., Henning C. // ChemPhysChem. 2015. Vol. 16. P. 2653. doi: 10.1002/cphc.201500283
- Turanov A.N., Karandashev V.K. // Solv. Extr. Ion Exch. 2023. Vol. 41. P. 885. doi: 10.1080/07366299.2023.2249952
- Katsuta S., Watanabe Y., Araki Y., Kudo Y. // ACS Sust. Chem. Eng. 2016. Vol. 4. P. 564. doi: 10.1021/acssuschemeng.5b00976
- Turanov A.N., Karandashev V.K., Kostikova G.V., Fedoseev A.M. // Radiochemistry. 2023. Vol. 65. N 1. P. 39. doi: 10.1134/S106636222301006X
- Стоянов Е.С., Воробьева Т.П., Смирнов И.В. // ЖСХ. 2003. Т. 44. № 3. С. 414.
- Stoyanov E.S., Smirnov I.V., Fedotov M.A. // J. Phys. Chem. (A). 2006. Vol. 110. P. 9505. doi: 10.1021/jp0609838
- Stoyanov E.S., Smirnov I.V. // J. Mol. Struct. 2005. Vol. 740. P. 9. doi: 10.1016/j.molstruct.2004.12.037
- Binnemans K. // Chem. Rev. 2007. Vol. 107. P. 2593. doi: 10.1021/cr050979c
- Sharova E.V., Artyushin O.I., Nelyubina Yu.V., Lyssenko K.A., Passechnik M.P., Odinets I.L. // Russ. Chem. Bull. 2008. Vol. 57. N 9. P. 1890. doi: 10.1007/s11172-008-0255-9
- Yarkevich A.N., Brel V.K., Makhaeva G.F., Serebryakova O.G., Boltneva N.P., Kovaleva N.V. // Russ. J. Gen. Chem. 2015. Vol. 85. N 7. P. 1644. doi: 10.1134/S1070363215070129
- Turanov A.N., Karandashev V.K., Kharitonov A.N., Lezhnev A.N., Safronova Z.V., Yarkevich A.N., Tsvetkov E.N. // Russ. J. Gen. Chem. 1999. Vol. 69. N 7. P. 1068.
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