Iron Tricarbonyl Complexes Based on N,N'-Disubstituted Phenanthrenediimines

G. G. Kazakov; Казаков Г. Г.; N. O. Druzhkov; Дружков Н. О.; E. V. Baranov; Баранов Е. В.; V. K. Cherkasov; Черкасов В. К.

doi:10.31857/S0132344X22600205

Iron Tricarbonyl Complexes Based on N,N'-Disubstituted Phenanthrenediimines

Authors: Kazakov G.G.¹^,2, Druzhkov N.O.¹, Baranov E.V.¹, Cherkasov V.K.¹^,2
Affiliations:
1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia
2. Lobachevskii State University, Nizhny Novgorod, Russia
Issue: Vol 49, No 3 (2023)
Pages: 131-137
Section: Articles
URL: https://journal-vniispk.ru/0132-344X/article/view/137269
DOI: https://doi.org/10.31857/S0132344X22600205
EDN: https://elibrary.ru/CTUFOK
ID: 137269

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Abstract
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Abstract

The oxidative addition of N,N'-disubstituted phenanthrenediimines to iron carbonyls was studied. The reactions of acceptor phenanthrenediimines with Fe2(CO)9 give iron(I) tricarbonyl complexes with anion-radical forms of the ligands. The synthesized compounds were characterized by NMR and IR spectroscopy. The structures of the complex based on N,N'-bis(3-trifluoromethylphenyl)phenanthrenediimine and imidazol-2-one ligand was established by X-ray diffraction (XRD) (CIF files СCDC nos. 2173471 and 2173472, respectively).

Keywords

phenanthrenediimine, iron(I), iron carbonyl, XRD

References

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