Synthesis and optical properties of a heterocarboxylate complex with metalcore Zn2Eu

M. A. Uvarova; Уварова М. А.; I. V. Taidakov; Тайдаков И. В.; M. A. Shmelev; Шмелев М. А.; S. E. Nefedov; Нефедов С. Е.; I. L. Eremenko; Еременко И. Л.

doi:10.31857/S0132344X23700329

Synthesis and optical properties of a heterocarboxylate complex with metalcore Zn2Eu

Authors: Uvarova M.A.¹, Taidakov I.V.²^,3, Shmelev M.A.¹, Nefedov S.E.⁴, Eremenko I.L.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
2. Lebedev Physics Institute, Russian Academy of Sciences, 119991, Moscow, Russia
3. Plekhanov Russian Economic University, 117997, Moscow, Russia
4. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
Issue: Vol 49, No 12 (2023)
Pages: 744-751
Section: Articles
URL: https://journal-vniispk.ru/0132-344X/article/view/162366
DOI: https://doi.org/10.31857/S0132344X23700329
EDN: https://elibrary.ru/HQGFDW
ID: 162366

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Abstract
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Abstract

It has been shown that boiling aqueous europium(III) acetate with trifluoroacetic acid in a dioxane-acetonitrile mixture leads to the formation of a polymer {[Eu(μ-OOCCF3)3(OH2)2]}n (I) containing solvate dioxane molecules. The interaction of I in CH2Cl2 with [Phen2Zn2(µ-OOCBut)2(OOCBut)2] (II) at room temperature forms a precipitate, recrystallization of which from acetonitrile gives an unusual trinuclear heterometallic heteroanionic complex Phen2Zn2Eu(µ3-OH)(OOCBut)4(OOCCF3 )2 (III). The structure of the obtained compounds was established according to X-ray diffraction data (CCDC No. 2235937-2235939). The optical properties of complex III were studied.

Keywords

trifluoroacetates, heterometallic complexes, europium, luminescence, phosphorescence, crystal structure

References

Shi Q., Zhang S., Wang Q. et al. // J. Mol. Struct. 2007. V. 837. P. 185.
Binnemans K. // Chem. Rev. 2009. V. 109. P. 4283.
Lu X.-Q., Feng W.-X, Hui Y.-N. et al. // Eur. J. Inorg. Chem. 2010. V. 18. P. 2714.
Yang X., Jones R. A., Wu Q. et al. // Polyhedron. 2006. V. 25. P. 271.
Lo W.-K., Wong W.-K., Wong W.-Y. et al. // Inorg. Chem. 2006. V. 45. P. 9315.
Lu X., Bi W., Chai W. et al. // New J. Chem. 2008. V. 32. P. 127.
Belousov Y.A., Kiskin M.A., Sidoruk A.V. et al. // Austr. J. Chem. 2022. V. 75. P. 572.
Colis J.C.F, Staples R., Tripp C. et al. // J. Phys. Chem. B. 2005. V. 109. P. 102.
Yang X., Jones R.A., Lynch V. et al. // Dalton Trans. 2005. № 5. P. 849.
Xu H.-B. Shi L.-X, Ma E. et al. // Chem. Commun. 2006. V. 15. P. 1601.
Chietal Y.-X. // J. Luminescence. 2011. V. 131. P. 1707.
Xu H. B., Zhong Y. T., Zhang W. X. et al. // Dalton Trans. 2010. V. 39. P. 5676.
Shmelev M.A., Gogoleva N.V., Sidorov A.A. et al. // In-org. Chim. Acta. 2021. 515. P. 120050.
Николаевский С.А., Ямбулатов Д.С., Старикова А.А. и др. // Коорд. химия. 2020. Т. 46. № 4. С. 241 (Nikolaevskii S.A., Yambulatov D.S., Starikova A.A. et al. // Russ. J. Coord. Chem. 2020. V. 46. № 4. P. 260). https://doi.org/10.1134/S1070328420040053
Kiskin M.A., Varaksina E.A., Taydakov I.V. et al. // I-norg. Chim. Acta. 2018. V. 482. P. 85. https://doi.org/10.1016/j.ica.2018.05.037
Егоров Е.Н., Михалева Е.А., Кискин М.А. и др. // Изв. АН. Сер. хим. 2013. № 10. С. 2141 (Egorov E.N., Kiskin M.A., Sidorov A.A. et al. // Rus. Chem. Bull. 2013. V. 62. № 10. P. 2141.) https://doi.org/10.1007/s11172-013-0313-9
Nikolaevskii S.A., Evstifeev I.S., Kiskin M.A et al. // Polyhedron. 2018. V. 152. P. 61. https://doi.org/6110.1016/j.poly.2018.06.021
Kiskin M.A., Dobrokhotova Zh.V., Bogomyakov A.S. et al. // Russ. Chem. Bull. 2016. V. 65. P. 1488. https://doi.org/10.1007/s11172-016-1475-z
Rastorguev A.A., Remova A.A., Romanenko G.V. et al. // J. Struct. Chem. 2001. V. 42. P. 907
Munasinghe H.N., Szlag R.G., Imer M.R., Rabuffetti F.A. // Inorg. Chem. 2022. V. 61. P. 5588. https://doi.org/10.1021/acs.inorgchem.2c00196
Соколова Н.П., Варанд В.Л., Романенко Г.В. и др. // Коорд. химия. 2003. Т. 29. № 5. С. 387 (Sokolova N.P., Varand V.L., Romanenko G.V. et al. // Russ. J. Coord. Chem. 2003. V. 29. P. 362). https://doi.org/10.1023/A:1023636120532
Belyi V.I., Rastorguev A.A., Remov A.A. et al. // J. Struct. Chem. 2004. V. 45. P. 130.
Уварова М.А., Нефедов С.Е. // Журн. неорган. химии. 2021. Т. 66. № 12. С. 1713 (Uvarova M.A., Nefedov S.E. // Russ. J. Inorg. Chem. 2021. V. 66. № 12. P. 1837). https://doi.org/10.1134/S0036023621120202
Boyle T.J., Yonemoto D.T., Sears J.M., Treadwell L.J. // Polyhedron. 2017. V. 131. P. 59.
Barja B., Baggio R., Garland M.T, Aramendia P.F. // Inorg. Chim. Acta. 2003. V. 346. P. 187.
Уварова М.А., Нефедов С.Е. // Журн. неорган. химии. 2021. Т. 66. № 6. С. 737 (Uvarova M.A., Nefedov S.E. // Russ. J. Inorg. Chem. 2021. V. 66. № 6. P. 839). https://doi.org/10.1134/S0036023621060206
Golubnichaya M.A., Sidorov A.A., Fomina I.G. et al. // Russ. Chem. Bull. 1999. V. 48. P. 1751.
SMART (control) and SAINT (integration). Software. Version 5.0. Madison (WI, USA): Bruker AXS Inc., 1997
Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D. // J. Appl. Cryst. 2015. V. 48. P. 3.
Spek A.L. // Acta Crystallogr. 2009. V. D65(2). P. 148.
Dolomanov O.V., Bourhis L.J., Gildea R.J et al. // J. A-ppl. Cryst. 2009. V. 42. P. 339.
Casanova D., Llunell M., Alemany P., Alvarez S. // Chem. Eur. J. 2005. V. 11. P. 1479.
Уварова М.А., Луценко И.А., Никифорова М.Е. и др. // Коорд. химия. 2022. № 8. С. 451 (Uvarova M.A., Lutsenko I.A., Nikiforova M.E. et al. // Russ. J. Coord. Chem. 2022. V. 48. P. 457). https://doi.org/10.1134/S1070328422080073
Уварова М.А., Нефедов С.Е. // Коорд. химия. 2020. Т. 46. № 9. С. 530 (Uvarova M.A., Nefedov S.E. // Russ. J. Coord. Chem. 2020. Т. 46. № 9. С. 608). https://doi.org/10.1134/S1070328420090079
Xiao Y., Huang P., Wang W. // J. Clust. Sci. 2015. V. 26. I. 4. P. 1091.
Dey D., Roy S., Purkayastha R.D. et al. // J. Molec. Struct. 2013. V. 1053. P. 127.
Бочкарев М.Н., Витухновский А.Г., Каткова М.А. Органические светоизлучающие диоды (OLED). Н. Новгород.: Деком., 2011. 359 с.