Reactions of palladium(II) chloride with monoiminoacenaphthenones

A. N. Lukoyanov; Лукоянов А. Н.; N. F. Romashev; Ромашев Н. Ф.; V. I. Komlyagina; Комлягина В. И.; V. V. Kokovkin; Коковкин В. В.; A. V. Cherkasov; Черкасов А. В.; A. L. Gushchin; Гущин А. Л.

doi:10.31857/S0132344X23600595

Reactions of palladium(II) chloride with monoiminoacenaphthenones

Authors: Lukoyanov A.N.¹, Romashev N.F.², Komlyagina V.I.²^,3, Kokovkin V.V.², Cherkasov A.V.¹, Gushchin A.L.²
Affiliations:
1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia
2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
3. Novosibirsk State University, Novosibirsk, Russia
Issue: Vol 49, No 12 (2023)
Pages: 760-766
Section: Articles
URL: https://journal-vniispk.ru/0132-344X/article/view/162368
DOI: https://doi.org/10.31857/S0132344X23600595
EDN: https://elibrary.ru/LGNPMA
ID: 162368

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

When PdCl2 reacts with [2,6-diisopropylphenyl]iminoacenaphthenone (dpp-mian) in dichloromethane, the compound 2[Pd(dpp-mian)Cl2]*[Pd(dpp-mian)2Cl2] (1) is formed. It contains two structural units: [Pd(dpp-mian)Cl2], in which dpp-mian is coordinated to Pd(II) in a bidentate-chelate manner by nitrogen and oxygen atoms, and [Pd(dpp-mian)2Cl2], in which two dpp-mian molecules are bonded to palladium only through a nitrogen atom. On the other hand, when PdCl2 interacts with [4-methoxyphenyl]iminoacenaphthenone (4-MeOPh-mian) in dichloromethane, a rearrangement of the ligand structure occurs, followed by the formation of the previously described in the literature complex of Pd(II) with 1,2-bis-[4-methoxyphenyl ]iminoacenaphthene (4-MeOPh-bian) of the composition [Pd(4-MeOPh-bian)Cl2] (2). Compound 1 was obtained for the first time and characterized by X-ray diffraction, as well as by X-ray diffraction, elemental analysis, IR spectroscopy and cyclic voltammetry.

Keywords

palladium, iminoacenaphthenones, X-ray diffraction analysis, complexes, synthesis, cyclic voltammetry

References

Khrizanforova V.V., Fayzullin R.R., Gerasimova T.P. et al. // Int. J. Mol. Sci. 2023. V. 24. № 10. P. 8667.
Razborov D.A., Lukoyanov A.N., Baranov E.V. et al. // Dalton Trans. 2015. V. 44. № 47. P. 20532.
Lukoyanov, A. N., Zvereva, Y. V., Parshina, D. A. et al. // Eur. J. Inorg. Chem. 2022. V. 2022. № 27. Art. e202200348
Lukoyanov A.N., Ulivanova E.A., Razborov D.A. et al. // Chem. Eur. J. 2019. V. 25. № 15. P. 3858.
Koptseva T.S., Moskalev M.V., Skatova A.A. et al. // Inorg. Chem. 2022. V. 61. № 1. P. 206.
Bernauer J., Pölker J., von Wangelin J. // ChemCatChem. 2022. V. 14. № 1. Art. e202101182
Yambulatov D.S., Nikolaevskii S.A., Kiskin M.A. et al. // Molecules. 2020. V. 25. № 9. P. 2054.
Romashev N.F., Bakaev I.V., Komlyagina V.I. et al. // J. Struct. Chem. 2022. V. 63. № 8. P. 1304.
Romashev N.F., Mirzaeva I.V., Bakaev I.V. et al. // J. Struct. Chem. 2022. V. 63. № 2. P. 242.
Romashev N.F., Bakaev I.V., Komlyagina V.I. et al. // Int. J. Mol. Sci. 2023. V. 24. № 13. P. 10457.
Komlyagina V.I., Romashev N.F., Besprozvannykh V.K. et al. // Inorg. Chem. 2023. V. 62. № 29. P. 11541.
Razborov D.A., Lukoyanov A.N., Makarov V.M. et al. // Russ. Chem. Bull. 2015. V. 64. № 10. P. 2377.
Anga S., Paul M., Naktode K. et al. // Z. Anorg. Allg. Chem. 2012. V. 638. № 9. P. 13115.
Lukoyanov A.N., Fomenko I.S., Gongola M.I. et al. // Molecules. 2021. V. 26. № 18. P. 5706.
Anga S., Pal T., Kottalanka R.K. et al. // Can. Chem. Trans. 2013. V. 1. № 2. P. 105.
Anga S., Rej S., Naktode K. et al. // J. Chem. Sci. 2015. V. 127. № 1. P. 103.
Gao B., Gao W., Wu Q. et al. // Organometallics. 2011. V. 30. № 20. P. 5480.
Carrington S.J., Chakraborty I., Mascharak P.K. // Dalton Trans. 2015. V. 44. № 31. P. 13828.
Hazari A.S., Das A., Ray R. et al. // Inorg. Chem. 2015. V. 54. № 10. P. 4998.
Visentin L.C., Ferreira L.C., Bordinhão J. et al. // J. Braz. Chem. Soc. 2010. V. 21. № 7. P. 1187.
Bhattacharjee J., Sachdeva M., Banerjee I. et al. // J. Chem. Sci. 2016. V. 128. № 6. P. 875.
Singha Hazari A., Ray R., Hoque M.A. et al. // Inorg. Chem. 2016. V. 55. № 16. P. 8160.
Tang X., Huang Y.T., Liu H. et al. // J. Organomet. Chem. 2013. V. 729. P. 95.
Фоменко Я.С., Надолинный В.А., Ефимов Н.Н. и др. // Коорд. Химия. 2019. V. 45. № 11. P. 672 (Fomenko I.S., Nadolinny V.A., Efimov N.N. et al. // Russ. J. Coord. Chem. 2019. V. 45. P. 776). https://doi.org/10.1134/S1070328419110022
Komlyagina V.I., Romashev N.F., Kokovkin V.V. et al. // Molecules. 2022. V. 27. № 20. P. 6961.
Kuznetsova A.A., Volchek V.V., Yanshole V.V. et al. // Inorg. Chem. 2022. V. 61. № 37. P. 14560.
APEX3. SAINT. Madison (WI, USA): Bruker AXS Inc., 2018.
Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D. // J. Appl. Crystallogr. 2015. V. 48. № 1. P. 3.
Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
Sheldrick G.M. // Acta Crystallogr. A.2015. V. 71. № 1. P. 3.
Coventry D.N., Batsanov A.S., Goeta A.E. et al. // Polyhedron. 2004. V. 23. № 17. P. 2789.
Romashev N.F., Gushchin A.L., Fomenko I.S. et al. // Polyhedron. 2019. V. 173. P. 114110.
Romashev N.F., Abramov P.A., Bakaev I.V. et al. // Inorg. Chem. 2022. V. 61. № 4. P. 2105.
Wang J., Ganguly R., Yongxin L. et al. // Dalton Trans. 2016. V. 45. № 19. P. 7941.