Trimethylammonium dichloro-hexachlorotellurate(IV): crystal structure and features of non-covalent interactions of Cl···Cl

A. N. Usoltsev; Усольцев А. Н.; A. A. Sonina; Сонина А. А.; N. A. Korobeinikov; Коробейников Н. А.; S. A. Adonin; Адонин С. А.

doi:10.31857/S0132344X23600030

Trimethylammonium dichloro-hexachlorotellurate(IV): crystal structure and features of non-covalent interactions of Cl···Cl

Авторлар: Usoltsev A.N.¹, Sonina A.A.², Korobeinikov N.A.¹^,3, Adonin S.A.¹^,4
Мекемелер:
1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
3. Novosibirsk State University, Novosibirsk, Russia
4. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Шығарылым: Том 49, № 12 (2023)
Беттер: 767-771
Бөлім: Articles
URL: https://journal-vniispk.ru/0132-344X/article/view/162369
DOI: https://doi.org/10.31857/S0132344X23600030
EDN: https://elibrary.ru/LOZEVL
ID: 162369

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат
Рұқсат жабық

Рұқсат берілді
Рұқсат жабық

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Аннотация
Авторлар туралы
Әдебиет тізімі
Қосымша файлдар
Статистика

Аннотация

By the reaction of tellurium(IV) oxide with trimethylammonium chloride in the presence of chlorine gas in concentrated hydrochloric acid, supramolecular dichloro-hexachlorotellurate (Me3NH)2{[TeCl6](Cl2)} (I) was obtained, the structure of which was determined by X-ray diffraction. Based on elemental and X-ray phase analysis data, a conclusion was made about the limited stability of the resulting compound. The features of non-covalent Cl···Cl interactions in the crystal structure of this compound were studied by Raman spectroscopy (Raman).

Негізгі сөздер

tellurium, halide complexes, X-ray diffraction analysis, halogen bond, non-covalent interactions

Әдебиет тізімі

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